mer-(4-Aminobenzenesulfonato-κN)-triaqua(1,10-phenanthroline-κ2N, N')-cobalt(II) chloride

Both coordination and hydrogen bonds contribute to networking in the supramolecular title compound, [Co(C(6)H(6)NO(3)S)(C(12)H(8)N(2))(H(2)O)(3)]Cl, which contains a discrete [Co(C(6)H(6)NO(3)S)(C(12)H(8)N(2))(H(2)O)(3)](+) complex cation, formed by one 4-aminobenzenesulfonate ligand, one 1,10-phena...

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Bibliographic Details
Published in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2004-01, Vol.60 (Pt 1), p.m30-m32
Main Authors: HUANG, Ming-Hua, BI, Li-Hua, DONG, Shao-Jun
Format: Article
Language:English
Subjects:
Condensed matter: structure, mechanical and thermal properties
Crystalline state (including molecular motions in solids)
Exact sciences and technology
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
Theory of crystal structure, crystal symmetry
calculations and modeling
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Summary:Both coordination and hydrogen bonds contribute to networking in the supramolecular title compound, [Co(C(6)H(6)NO(3)S)(C(12)H(8)N(2))(H(2)O)(3)]Cl, which contains a discrete [Co(C(6)H(6)NO(3)S)(C(12)H(8)N(2))(H(2)O)(3)](+) complex cation, formed by one 4-aminobenzenesulfonate ligand, one 1,10-phenanthroline ligand and three coordinated water molecules, together with one uncoordinated chloride anion. These discrete cations and chloride anions are connected by hydrogen-bonding interactions into a two-dimensional supramolecular motif. Further hydrogen-bonding interactions consolidate the structural architecture and extend the two-dimensional supramolecular structure into a three-dimensional network.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270103026957