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mer-(4-Aminobenzenesulfonato-κN)-triaqua(1,10-phenanthroline-κ2N, N')-cobalt(II) chloride

Both coordination and hydrogen bonds contribute to networking in the supramolecular title compound, [Co(C(6)H(6)NO(3)S)(C(12)H(8)N(2))(H(2)O)(3)]Cl, which contains a discrete [Co(C(6)H(6)NO(3)S)(C(12)H(8)N(2))(H(2)O)(3)](+) complex cation, formed by one 4-aminobenzenesulfonate ligand, one 1,10-phena...

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Published in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2004-01, Vol.60 (Pt 1), p.m30-m32
Main Authors: HUANG, Ming-Hua, BI, Li-Hua, DONG, Shao-Jun
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container_title Acta crystallographica. Section C, Crystal structure communications
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BI, Li-Hua
DONG, Shao-Jun
description Both coordination and hydrogen bonds contribute to networking in the supramolecular title compound, [Co(C(6)H(6)NO(3)S)(C(12)H(8)N(2))(H(2)O)(3)]Cl, which contains a discrete [Co(C(6)H(6)NO(3)S)(C(12)H(8)N(2))(H(2)O)(3)](+) complex cation, formed by one 4-aminobenzenesulfonate ligand, one 1,10-phenanthroline ligand and three coordinated water molecules, together with one uncoordinated chloride anion. These discrete cations and chloride anions are connected by hydrogen-bonding interactions into a two-dimensional supramolecular motif. Further hydrogen-bonding interactions consolidate the structural architecture and extend the two-dimensional supramolecular structure into a three-dimensional network.
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source Wiley-Blackwell Read & Publish Collection; Alma/SFX Local Collection
subjects Condensed matter: structure, mechanical and thermal properties
Crystalline state (including molecular motions in solids)
Exact sciences and technology
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
Theory of crystal structure, crystal symmetry
calculations and modeling
title mer-(4-Aminobenzenesulfonato-κN)-triaqua(1,10-phenanthroline-κ2N, N')-cobalt(II) chloride
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