Inherent helicity in an extended tris-bipyridyl molecular cage

A new molecular cage incorporating three bipyridyl units has been synthesised by a conventional multi-step procedure as well as, much more efficiently, by a Ni(ii) template procedure; an X-ray structure of the nickel complex shows that it adopts an exo configuration of each of the bridgehead nitroge...

Full description

Saved in:
Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2004-01 (2), p.152-153
Main Authors: Perkins, David F, Lindoy, Leonard F, Meehan, George V, Turner, Peter
Format: Article
Language:English
Citations: Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c299t-e1f47c2d5e1f411e696af75db71db3e38b7df8159adcdfb238648463261fc1e93
cites
container_end_page 153
container_issue 2
container_start_page 152
container_title Chemical communications (Cambridge, England)
container_volume
creator Perkins, David F
Lindoy, Leonard F
Meehan, George V
Turner, Peter
description A new molecular cage incorporating three bipyridyl units has been synthesised by a conventional multi-step procedure as well as, much more efficiently, by a Ni(ii) template procedure; an X-ray structure of the nickel complex shows that it adopts an exo configuration of each of the bridgehead nitrogen lone pairs, the central metal ion acts to promote a triple helical twist that extends [similar]22 [Angstrom] along the axial length of the molecule.
doi_str_mv 10.1039/b312716h
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_80110496</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>80110496</sourcerecordid><originalsourceid>FETCH-LOGICAL-c299t-e1f47c2d5e1f411e696af75db71db3e38b7df8159adcdfb238648463261fc1e93</originalsourceid><addsrcrecordid>eNpFkEtLw0AUhQdRbK2Cv0BmJW6iuZlXZiNI8VEouFFwFyYzN3YkjzqTgPn3prTi2Zyz-DiLj5BLSG8hZfquZJApkJsjMgcmeSJ4_nG820IninExI2cxfqVTQOSnZAZcMSUyPif3q3aDAduebrD21vcj9S01LcWfHluHjvbBx6T02zF4N9a06Wq0Q20CteYTz8lJZeqIF4dekPenx7flS7J-fV4tH9aJzbTuE4SKK5s5sRsAKLU0lRKuVOBKhiwvlatyENo466oyY7nkOZcsk1BZQM0W5Hr_uw3d94CxLxofLda1abEbYpGnACnXcgJv9qANXYwBq2IbfGPCWEBa7FwVf64m9OrwOZQNun_wIIf9Amo-ZBI</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>80110496</pqid></control><display><type>article</type><title>Inherent helicity in an extended tris-bipyridyl molecular cage</title><source>Royal Society of Chemistry: Jisc Collections: Journals Archive 1841-2007 (2019-2023)</source><creator>Perkins, David F ; Lindoy, Leonard F ; Meehan, George V ; Turner, Peter</creator><creatorcontrib>Perkins, David F ; Lindoy, Leonard F ; Meehan, George V ; Turner, Peter</creatorcontrib><description>A new molecular cage incorporating three bipyridyl units has been synthesised by a conventional multi-step procedure as well as, much more efficiently, by a Ni(ii) template procedure; an X-ray structure of the nickel complex shows that it adopts an exo configuration of each of the bridgehead nitrogen lone pairs, the central metal ion acts to promote a triple helical twist that extends [similar]22 [Angstrom] along the axial length of the molecule.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/b312716h</identifier><identifier>PMID: 14737524</identifier><language>eng</language><publisher>England</publisher><ispartof>Chemical communications (Cambridge, England), 2004-01 (2), p.152-153</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c299t-e1f47c2d5e1f411e696af75db71db3e38b7df8159adcdfb238648463261fc1e93</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/14737524$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Perkins, David F</creatorcontrib><creatorcontrib>Lindoy, Leonard F</creatorcontrib><creatorcontrib>Meehan, George V</creatorcontrib><creatorcontrib>Turner, Peter</creatorcontrib><title>Inherent helicity in an extended tris-bipyridyl molecular cage</title><title>Chemical communications (Cambridge, England)</title><addtitle>Chem Commun (Camb)</addtitle><description>A new molecular cage incorporating three bipyridyl units has been synthesised by a conventional multi-step procedure as well as, much more efficiently, by a Ni(ii) template procedure; an X-ray structure of the nickel complex shows that it adopts an exo configuration of each of the bridgehead nitrogen lone pairs, the central metal ion acts to promote a triple helical twist that extends [similar]22 [Angstrom] along the axial length of the molecule.</description><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNpFkEtLw0AUhQdRbK2Cv0BmJW6iuZlXZiNI8VEouFFwFyYzN3YkjzqTgPn3prTi2Zyz-DiLj5BLSG8hZfquZJApkJsjMgcmeSJ4_nG820IninExI2cxfqVTQOSnZAZcMSUyPif3q3aDAduebrD21vcj9S01LcWfHluHjvbBx6T02zF4N9a06Wq0Q20CteYTz8lJZeqIF4dekPenx7flS7J-fV4tH9aJzbTuE4SKK5s5sRsAKLU0lRKuVOBKhiwvlatyENo466oyY7nkOZcsk1BZQM0W5Hr_uw3d94CxLxofLda1abEbYpGnACnXcgJv9qANXYwBq2IbfGPCWEBa7FwVf64m9OrwOZQNun_wIIf9Amo-ZBI</recordid><startdate>20040121</startdate><enddate>20040121</enddate><creator>Perkins, David F</creator><creator>Lindoy, Leonard F</creator><creator>Meehan, George V</creator><creator>Turner, Peter</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20040121</creationdate><title>Inherent helicity in an extended tris-bipyridyl molecular cage</title><author>Perkins, David F ; Lindoy, Leonard F ; Meehan, George V ; Turner, Peter</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c299t-e1f47c2d5e1f411e696af75db71db3e38b7df8159adcdfb238648463261fc1e93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Perkins, David F</creatorcontrib><creatorcontrib>Lindoy, Leonard F</creatorcontrib><creatorcontrib>Meehan, George V</creatorcontrib><creatorcontrib>Turner, Peter</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Perkins, David F</au><au>Lindoy, Leonard F</au><au>Meehan, George V</au><au>Turner, Peter</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Inherent helicity in an extended tris-bipyridyl molecular cage</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><addtitle>Chem Commun (Camb)</addtitle><date>2004-01-21</date><risdate>2004</risdate><issue>2</issue><spage>152</spage><epage>153</epage><pages>152-153</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>A new molecular cage incorporating three bipyridyl units has been synthesised by a conventional multi-step procedure as well as, much more efficiently, by a Ni(ii) template procedure; an X-ray structure of the nickel complex shows that it adopts an exo configuration of each of the bridgehead nitrogen lone pairs, the central metal ion acts to promote a triple helical twist that extends [similar]22 [Angstrom] along the axial length of the molecule.</abstract><cop>England</cop><pmid>14737524</pmid><doi>10.1039/b312716h</doi><tpages>2</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1359-7345
ispartof Chemical communications (Cambridge, England), 2004-01 (2), p.152-153
issn 1359-7345
1364-548X
language eng
recordid cdi_proquest_miscellaneous_80110496
source Royal Society of Chemistry: Jisc Collections: Journals Archive 1841-2007 (2019-2023)
title Inherent helicity in an extended tris-bipyridyl molecular cage
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-05T23%3A56%3A01IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Inherent%20helicity%20in%20an%20extended%20tris-bipyridyl%20molecular%20cage&rft.jtitle=Chemical%20communications%20(Cambridge,%20England)&rft.au=Perkins,%20David%20F&rft.date=2004-01-21&rft.issue=2&rft.spage=152&rft.epage=153&rft.pages=152-153&rft.issn=1359-7345&rft.eissn=1364-548X&rft_id=info:doi/10.1039/b312716h&rft_dat=%3Cproquest_cross%3E80110496%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c299t-e1f47c2d5e1f411e696af75db71db3e38b7df8159adcdfb238648463261fc1e93%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=80110496&rft_id=info:pmid/14737524&rfr_iscdi=true