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Factors influencing solvent adduct formation by calixarenes in the solid state

Structural studies of seven very differently functionalised derivatives of calix[4]arene have been used to provide an analysis of the numerous factors which may influence solvent adduct formation by calixarenes. Evidence is presented that even where a solvent guest is included within the calixarene...

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Bibliographic Details
Published in:Organic & biomolecular chemistry 2004-02, Vol.2 (3), p.387-396
Main Authors: Asfari, Zouhair, Bilyk, Alexander, Bond, Cameron, Harrowfield, Jack M, Koutsantonis, George A, Lengkeek, Nigel, Mocerino, Mauro, Skelton, Brian W, Sobolev, Alexandre N, Strano, Simon, Vicens, Jacques, White, Allan H
Format: Article
Language:English
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Summary:Structural studies of seven very differently functionalised derivatives of calix[4]arene have been used to provide an analysis of the numerous factors which may influence solvent adduct formation by calixarenes. Evidence is presented that even where a solvent guest is included within the calixarene cavity, interactions solely within the cavity cannot be seen as the sole influences upon the guest position and orientation.
ISSN:1477-0520
1477-0539
DOI:10.1039/b308214h