A Zeolitic Organo−Metallophosphate Hybrid Material with Bimodal Porosity

The first metal carboxylatophosphate, NTHU-2, contains inorganic ZnHPO4 layers linked by BDC units (BDC = 1,4-benzene dicarboxylate or terephthalic anion); the three-dimensional anionic framework has large pores with the smallest diameter being 1.36 nm; N2 sorption isotherms reveal both micro- and m...

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Bibliographic Details
Published in:Journal of the American Chemical Society 2004-02, Vol.126 (5), p.1320-1321
Main Authors: Liao, Yueh-Chun, Liao, Fen-Ling, Chang, Wei-Kuo, Wang, Sue-Lein
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
General and physical chemistry
Ion-exchange
Surface physical chemistry
Zeolites: preparations and properties
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Summary:The first metal carboxylatophosphate, NTHU-2, contains inorganic ZnHPO4 layers linked by BDC units (BDC = 1,4-benzene dicarboxylate or terephthalic anion); the three-dimensional anionic framework has large pores with the smallest diameter being 1.36 nm; N2 sorption isotherms reveal both micro- and mesoporosity; the new material is photoluminescent and disassembles in water wherein the discharged organic fragments form mixed crystals.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja0390146