A Zeolitic Organo−Metallophosphate Hybrid Material with Bimodal Porosity

The first metal carboxylatophosphate, NTHU-2, contains inorganic ZnHPO4 layers linked by BDC units (BDC = 1,4-benzene dicarboxylate or terephthalic anion); the three-dimensional anionic framework has large pores with the smallest diameter being 1.36 nm; N2 sorption isotherms reveal both micro- and m...

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Published in:Journal of the American Chemical Society 2004-02, Vol.126 (5), p.1320-1321
Main Authors: Liao, Yueh-Chun, Liao, Fen-Ling, Chang, Wei-Kuo, Wang, Sue-Lein
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
General and physical chemistry
Ion-exchange
Surface physical chemistry
Zeolites: preparations and properties
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cited_by cdi_FETCH-LOGICAL-a294t-2ac773256ebc7e99cc527202dcc1155d605d7bde0f9ea693655acafb8fd92ca13
cites cdi_FETCH-LOGICAL-a294t-2ac773256ebc7e99cc527202dcc1155d605d7bde0f9ea693655acafb8fd92ca13
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container_title Journal of the American Chemical Society
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creator Liao, Yueh-Chun
Liao, Fen-Ling
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description The first metal carboxylatophosphate, NTHU-2, contains inorganic ZnHPO4 layers linked by BDC units (BDC = 1,4-benzene dicarboxylate or terephthalic anion); the three-dimensional anionic framework has large pores with the smallest diameter being 1.36 nm; N2 sorption isotherms reveal both micro- and mesoporosity; the new material is photoluminescent and disassembles in water wherein the discharged organic fragments form mixed crystals.
doi_str_mv 10.1021/ja0390146
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source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Chemistry
Exact sciences and technology
General and physical chemistry
Ion-exchange
Surface physical chemistry
Zeolites: preparations and properties
title A Zeolitic Organo−Metallophosphate Hybrid Material with Bimodal Porosity
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