High heat of hydrogen adsorption and guest-responsive magnetic modulation in a 3D porous pillared-layer coordination framework

A bimetallic pillared-layer coordination framework {[Mn(3)(bipy)(3)(H(2)O)(4)][Cr(CN)(6)](2)·2(bipy)·4(H(2)O)}(n) has been constructed using a cyanometallate anion ([Cr(CN)(6)](3-)) and an organic linker (4,4'-bipyridyl) that provides high heat of hydrogen adsorption (∼11.5 kJ mol(-1)) and show...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2011-01, Vol.47 (1), p.538-540
Main Authors: Hazra, Arpan, Kanoo, Prakash, Maji, Tapas Kumar
Format: Article
Language:English
Subjects:
Adsorption
Hot Temperature
Hydrogen - chemistry
Magnetics
Models, Molecular
Organometallic Compounds - chemistry
Porosity
Surface Properties
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Summary:A bimetallic pillared-layer coordination framework {[Mn(3)(bipy)(3)(H(2)O)(4)][Cr(CN)(6)](2)·2(bipy)·4(H(2)O)}(n) has been constructed using a cyanometallate anion ([Cr(CN)(6)](3-)) and an organic linker (4,4'-bipyridyl) that provides high heat of hydrogen adsorption (∼11.5 kJ mol(-1)) and shows guest dependent magnetic modulation.
ISSN:1364-548X
DOI:10.1039/c0cc02490b