Temperature dependent selective gas sorption of the microporous metal-imidazolate framework [Cu(L)] [H2L = 1,4-di(1H-imidazol-4-yl)benzene]

A highly stable copper(II) microporous framework with cylindrical channels constructed from 1,4-di(1H-imidazol-4-yl)benzene (H(2)L) and CuCl(2)·2H(2)O is composed of Cu(II)-imidazolate tubes interconnected by the 1,4-phenylene group of L(2-), and shows temperature dependent selective gas sorption pr...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2011-01, Vol.47 (2), p.752-754
Main Authors: Chen, Shui-Sheng, Chen, Min, Takamizawa, Satoshi, Chen, Man-Sheng, Su, Zhi, Sun, Wei-Yin
Format: Article
Language:English
Subjects:
Absorption
Benzimidazoles - chemistry
Channels
CONNECTORS (ELECTRICAL)
Construction
Copper - chemistry
Gases - chemistry
Imidazoles - chemistry
PORE SIZE AND SHAPE
POROSITY
Sorption
Temperature
TUBE
Tubes
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Summary:A highly stable copper(II) microporous framework with cylindrical channels constructed from 1,4-di(1H-imidazol-4-yl)benzene (H(2)L) and CuCl(2)·2H(2)O is composed of Cu(II)-imidazolate tubes interconnected by the 1,4-phenylene group of L(2-), and shows temperature dependent selective gas sorption properties.
ISSN:1359-7345
1364-548X
DOI:10.1039/c0cc04085a