Penta-carbonyl-2κC-chlorido-1κCl-bis-[1(η)-cyclo-penta-dien-yl][μ(2)-oxido(meth-yl)methyl-ene-1:2κO:C]tungsten(0)zirconium(IV)

The title compound, [ZrW(C(5)H(5))(2)(C(2)H(3)O)Cl(CO)(5)] or [W(CO)(5)C(CH(3))OZr(C(5)H(5))(2)Cl], consists of two metal centres, with a (tungsten penta-carbon-yl)oxymethyl-carbene group coordinating as a monodentate ligand to the chloridozirconocene. The two halves of the mol-ecule are related by...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2008-09, Vol.64 (Pt 10), p.m1252-m1252
Main Authors: Esterhuysen, Catharine, Neveling, Arno, Luruli, Nyambeni, Kruger, Gert J, Cronje, Stephanie
Format: Article
Language:English
Online Access:Get full text
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Summary:The title compound, [ZrW(C(5)H(5))(2)(C(2)H(3)O)Cl(CO)(5)] or [W(CO)(5)C(CH(3))OZr(C(5)H(5))(2)Cl], consists of two metal centres, with a (tungsten penta-carbon-yl)oxymethyl-carbene group coordinating as a monodentate ligand to the chloridozirconocene. The two halves of the mol-ecule are related by a crystallographic mirror plane. Delocalization through the Zr-O-C=W unit is indicated by a short Zr-O distance and a nearly linear Zr-O-C angle.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536808028006