Synthesis of macrolide antibiotics. I. Stereospecific addition of methyllithium and methylmagnesium iodide to methyl .alpha.-D-xylo-hexopyranosid-4-ulose derivatives. Determination of the configuration at the branching carbon atom by carbon-13 nuclear magnetic resonance spectroscopy

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Bibliographic Details
Published in:Journal of organic chemistry 1974-05, Vol.39 (10), p.1379-1384
Main Authors: Miljkovic, Momcilo, Gligorijevic, Miodrag, Satoh, Toshio, Miljkovic, Dusan
Format: Article
Language:English
Subjects:
Anti-Bacterial Agents - chemical synthesis
Carbon Isotopes
Iodides
Lithium
Magnesium
Magnetic Resonance Spectroscopy
Methylglycosides
Organometallic Compounds
Pyrans - chemical synthesis
Stereoisomerism
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ISSN:0022-3263
1520-6904
DOI:10.1021/jo00926a012