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Performance of an oxygen-permeable membrane reactor for partial oxidation of methane in coke oven gas to syngas
Perovskite-type oxygen-permeable membrane reactors of BaCo 0.7Fe 0.2Nb 0.1O 3− δ packed with Ni-based catalyst had high oxygen permeability and could be used for syngas production by partial oxidation of methane in coke oven gas (COG). The BCFNO membrane itself had a poor catalytic activity to parti...
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| Published in: | Fuel (Guildford) 2011, Vol.90 (1), p.324-330 |
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| Main Authors: | , , , |
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| Language: | English |
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| container_end_page | 330 |
| container_issue | 1 |
| container_start_page | 324 |
| container_title | Fuel (Guildford) |
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| creator | Zhang, Yuwen Liu, Jiao Ding, Weizhong Lu, Xionggang |
| description | Perovskite-type oxygen-permeable membrane reactors of BaCo
0.7Fe
0.2Nb
0.1O
3−
δ
packed with Ni-based catalyst had high oxygen permeability and could be used for syngas production by partial oxidation of methane in coke oven gas (COG). The BCFNO membrane itself had a poor catalytic activity to partial oxidation of CH
4 in COG. After the catalyst was packed on the membrane surface, 92% of methane conversion, 90% of H
2 selectivity, 104% of CO selectivity and as high as 15
ml/cm
2/min of oxygen permeation flux were obtained at 1148
K. During continuously operating for 550
h at 1148
K, no degradation of performance of the BCFNO membrane reactor was observed under the condition of hydrogen-rich COG. The possible reaction pathways were proposed to be an oxidation-reforming process. The oxidation of H
2 in COG with the surface oxygen on the permeation side improves the oxygen flux through the membrane, and H
2O reacts with CH
4 by reforming reactions to form H
2 and CO. |
| doi_str_mv | 10.1016/j.fuel.2010.08.027 |
| format | article |
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0.7Fe
0.2Nb
0.1O
3−
δ
packed with Ni-based catalyst had high oxygen permeability and could be used for syngas production by partial oxidation of methane in coke oven gas (COG). The BCFNO membrane itself had a poor catalytic activity to partial oxidation of CH
4 in COG. After the catalyst was packed on the membrane surface, 92% of methane conversion, 90% of H
2 selectivity, 104% of CO selectivity and as high as 15
ml/cm
2/min of oxygen permeation flux were obtained at 1148
K. During continuously operating for 550
h at 1148
K, no degradation of performance of the BCFNO membrane reactor was observed under the condition of hydrogen-rich COG. The possible reaction pathways were proposed to be an oxidation-reforming process. The oxidation of H
2 in COG with the surface oxygen on the permeation side improves the oxygen flux through the membrane, and H
2O reacts with CH
4 by reforming reactions to form H
2 and CO.</description><identifier>ISSN: 0016-2361</identifier><identifier>EISSN: 1873-7153</identifier><identifier>DOI: 10.1016/j.fuel.2010.08.027</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Alternative fuels. Production and utilization ; Applied sciences ; Catalysts ; Cog ; Coke oven gas ; Energy ; Energy. Thermal use of fuels ; Exact sciences and technology ; Flux ; Fuels ; Hydrogen ; Hydrogen production ; Membranes ; Methane ; Mixed-conducting oxygen-permeable membrane reactor ; Oxidation ; Permeation ; Reaction pathways ; Reactors</subject><ispartof>Fuel (Guildford), 2011, Vol.90 (1), p.324-330</ispartof><rights>2010</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c395t-7eb08d3fe0df9b1f2f3f26dd51300f9df554cb196a71da6685aa56f8b765c4db3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,4024,27923,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23500667$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Zhang, Yuwen</creatorcontrib><creatorcontrib>Liu, Jiao</creatorcontrib><creatorcontrib>Ding, Weizhong</creatorcontrib><creatorcontrib>Lu, Xionggang</creatorcontrib><title>Performance of an oxygen-permeable membrane reactor for partial oxidation of methane in coke oven gas to syngas</title><title>Fuel (Guildford)</title><description>Perovskite-type oxygen-permeable membrane reactors of BaCo
0.7Fe
0.2Nb
0.1O
3−
δ
packed with Ni-based catalyst had high oxygen permeability and could be used for syngas production by partial oxidation of methane in coke oven gas (COG). The BCFNO membrane itself had a poor catalytic activity to partial oxidation of CH
4 in COG. After the catalyst was packed on the membrane surface, 92% of methane conversion, 90% of H
2 selectivity, 104% of CO selectivity and as high as 15
ml/cm
2/min of oxygen permeation flux were obtained at 1148
K. During continuously operating for 550
h at 1148
K, no degradation of performance of the BCFNO membrane reactor was observed under the condition of hydrogen-rich COG. The possible reaction pathways were proposed to be an oxidation-reforming process. The oxidation of H
2 in COG with the surface oxygen on the permeation side improves the oxygen flux through the membrane, and H
2O reacts with CH
4 by reforming reactions to form H
2 and CO.</description><subject>Alternative fuels. Production and utilization</subject><subject>Applied sciences</subject><subject>Catalysts</subject><subject>Cog</subject><subject>Coke oven gas</subject><subject>Energy</subject><subject>Energy. Thermal use of fuels</subject><subject>Exact sciences and technology</subject><subject>Flux</subject><subject>Fuels</subject><subject>Hydrogen</subject><subject>Hydrogen production</subject><subject>Membranes</subject><subject>Methane</subject><subject>Mixed-conducting oxygen-permeable membrane reactor</subject><subject>Oxidation</subject><subject>Permeation</subject><subject>Reaction pathways</subject><subject>Reactors</subject><issn>0016-2361</issn><issn>1873-7153</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9kUtr3DAURkVJoJPHH-hKm9JsPL2yRg9DNyWkDwgki2QtZOkq1dS2ppInZP59ZSZkmZWEON-nyz2EfGKwZsDk1-067HFYt1AfQK-hVR_IimnFG8UEPyErqFTTcsk-krNStgCgtNisSLrHHFIe7eSQpkDtRNPL4QmnZod5RNsPSEcc-2wnpBmtm1OmNUB3Ns_RDpWO3s4xTUt6xPnPAsaJuvS3Fj7jRJ9soXOi5TDV2wU5DXYoePl6npPHHzcP17-a27ufv6-_3zaOd2JuFPagPQ8IPnQ9C23goZXeC8YBQueDEBvXs05axbyVUgtrhQy6V1K4je_5Ofly7N3l9G-PZTZjLA6HoY6X9sVozlqQknWVvHqXZEopJjutZEXbI-pyKiVjMLscR5sPhoFZPJitWTyYxYMBbaqHGvr82m-Ls0Oom3SxvCVbLqAOsnDfjhzWtTxHzKa4iFWLjxndbHyK733zH_eQn8Y</recordid><startdate>2011</startdate><enddate>2011</enddate><creator>Zhang, Yuwen</creator><creator>Liu, Jiao</creator><creator>Ding, Weizhong</creator><creator>Lu, Xionggang</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SU</scope><scope>7TB</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>L7M</scope><scope>7ST</scope><scope>SOI</scope></search><sort><creationdate>2011</creationdate><title>Performance of an oxygen-permeable membrane reactor for partial oxidation of methane in coke oven gas to syngas</title><author>Zhang, Yuwen ; Liu, Jiao ; Ding, Weizhong ; Lu, Xionggang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c395t-7eb08d3fe0df9b1f2f3f26dd51300f9df554cb196a71da6685aa56f8b765c4db3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Alternative fuels. Production and utilization</topic><topic>Applied sciences</topic><topic>Catalysts</topic><topic>Cog</topic><topic>Coke oven gas</topic><topic>Energy</topic><topic>Energy. Thermal use of fuels</topic><topic>Exact sciences and technology</topic><topic>Flux</topic><topic>Fuels</topic><topic>Hydrogen</topic><topic>Hydrogen production</topic><topic>Membranes</topic><topic>Methane</topic><topic>Mixed-conducting oxygen-permeable membrane reactor</topic><topic>Oxidation</topic><topic>Permeation</topic><topic>Reaction pathways</topic><topic>Reactors</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Yuwen</creatorcontrib><creatorcontrib>Liu, Jiao</creatorcontrib><creatorcontrib>Ding, Weizhong</creatorcontrib><creatorcontrib>Lu, Xionggang</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Environmental Engineering Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Environment Abstracts</collection><collection>Environment Abstracts</collection><jtitle>Fuel (Guildford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Yuwen</au><au>Liu, Jiao</au><au>Ding, Weizhong</au><au>Lu, Xionggang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Performance of an oxygen-permeable membrane reactor for partial oxidation of methane in coke oven gas to syngas</atitle><jtitle>Fuel (Guildford)</jtitle><date>2011</date><risdate>2011</risdate><volume>90</volume><issue>1</issue><spage>324</spage><epage>330</epage><pages>324-330</pages><issn>0016-2361</issn><eissn>1873-7153</eissn><abstract>Perovskite-type oxygen-permeable membrane reactors of BaCo
0.7Fe
0.2Nb
0.1O
3−
δ
packed with Ni-based catalyst had high oxygen permeability and could be used for syngas production by partial oxidation of methane in coke oven gas (COG). The BCFNO membrane itself had a poor catalytic activity to partial oxidation of CH
4 in COG. After the catalyst was packed on the membrane surface, 92% of methane conversion, 90% of H
2 selectivity, 104% of CO selectivity and as high as 15
ml/cm
2/min of oxygen permeation flux were obtained at 1148
K. During continuously operating for 550
h at 1148
K, no degradation of performance of the BCFNO membrane reactor was observed under the condition of hydrogen-rich COG. The possible reaction pathways were proposed to be an oxidation-reforming process. The oxidation of H
2 in COG with the surface oxygen on the permeation side improves the oxygen flux through the membrane, and H
2O reacts with CH
4 by reforming reactions to form H
2 and CO.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.fuel.2010.08.027</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0016-2361 |
| ispartof | Fuel (Guildford), 2011, Vol.90 (1), p.324-330 |
| issn | 0016-2361 1873-7153 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_831206619 |
| source | ScienceDirect Freedom Collection 2022-2024 |
| subjects | Alternative fuels. Production and utilization Applied sciences Catalysts Cog Coke oven gas Energy Energy. Thermal use of fuels Exact sciences and technology Flux Fuels Hydrogen Hydrogen production Membranes Methane Mixed-conducting oxygen-permeable membrane reactor Oxidation Permeation Reaction pathways Reactors |
| title | Performance of an oxygen-permeable membrane reactor for partial oxidation of methane in coke oven gas to syngas |
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