Characterization of primary thermal degradation features of lignocellulosic biomass after removal of inorganic metals by diverse solvents

• Published in: Bioresource technology 2011-02, Vol.102 (3), p.3437-3444
• Main Authors: Eom, In-Yong, Kim, Kwang-Ho, Kim, Jae-Young, Lee, Soo-Min, Yeo, Hwan-Myung, Choi, In-Gyu, Choi, Joon-Weon
• Format: Article
• Language: English
• Subjects: Analytical Py-GC/MS; Biological and medical sciences; Demineralization; Fundamental and applied biological sciences. Psychology; Hot Temperature; Inorganic Chemicals - chemistry; Inorganic Chemicals - isolation & purification; Inorganics; Lignin - analysis; Lignin - chemistry; Lignocellulosic biomass; Metals - chemistry; Metals - isolation & purification; Populus - chemistry; Pyrolytic mechanism; Solvents - chemistry; Wood - chemistry
• ISSN: 0960-8524; 1873-2976
• DOI: 10.1016/j.biortech.2010.10.056

Poplar wood powders were treated with distilled water, tap water, HCl and HF, respectively, to remove inorganics from the biomass and to investigate effect of demineralization processes on pyrolysis behavior of the biomass. TG and DTG revealed that maximum degradation temperatures rose slightly from 362°C for control to 372°C, 366°C and 368°C after demineralization with distilled water, HCl and HF, respectively. Maximum degradation rates also increased from 0.96%/°C for control to 1.15%/°C for HF-biomass, 1.23%/°C for DI-H2O-biomass, and 1.55%/°C for HCl-biomass. Analytical pyrolysis-GC/MS of demineralized biomasses produced approximately 45 pyrolysis compounds. Total amount of low molecular weight compounds, such as acetic acid, acetol, and 3-hydroxypropanal, was significantly lowered in the demineralized biomasses. But levoglucosan increased 2–10-folds in the demineralized biomasses. One of the features regarding lignin derivatives was the reduction of the amount of C6-type phenols, such as phenol, guaiacol, and syringol after demineralization.