Facile and Efficient Approach to Speed up Layer-by-Layer Assembly: Dipping in Agitated Solutions

• Published in: Langmuir 2011-01, Vol.27 (2), p.672-677
• Main Authors: Fu, Yu, Li, Su-Jing, Xu, Jing, Yang, Min, Zhang, Ji-Dong, Jiao, Yong-Hua, Zhang, Ji-Cheng, Zhang, Kai, Jia, Ying-Gang
• Format: Article
• Language: English
• Subjects: Chemistry; Exact sciences and technology; General and physical chemistry; Interfaces: Adsorption, Reactions, Films, Forces
• ISSN: 0743-7463; 1520-5827
• DOI: 10.1021/la104524k

A facile and efficient approach has been developed to speed up the fabrication of LBL films through sequential dipping in vigorously agitated solutions. By this agitated-dipping (AD) LBL technique, the multilayer films of PAH and PSS were fabricated. The resulting films were explored by UV−vis spectroscopy, X-ray reflectivity, and AFM. Meanwhile, the comparison of the AD and conventional LBL films was made, which demonstrated that AD LBL can decrease dipping time by more than 15 times without reducing film quality remarkably. In addition, to verify the generality of AD LBL, we studied the AD LBL films of PDDA/PSS and PAH/PAA preliminarily as well. AD LBL promotes the efficiency of conventional LBL greatly while preserving its most advantages, such as simplicity, cheapness, precise control, universality in substrates, recycling use of sample solutions, and so on. It would be a promising alternative to build up LBL films rapidly.