Aminotroponiminatozinc(I) Complexes: Syntheses and Spectroscopic Analyses

Aminotroponiminates—very effective ligands for the stabilization of low‐valent ZnI–ZnI bonded compounds (see scheme). For the first time a stretching motion of the ZnZn bond, which is almost uncoupled to other vibrations, was found in the Raman spectrum.

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Bibliographic Details
Published in:Chemistry : a European journal 2011-02, Vol.17 (6), p.1773-1777
Main Authors: Nayek, Hari Pada, Lühl, Anja, Schulz, Stephan, Köppe, Ralf, Roesky, Peter W.
Format: Article
Language:English
Subjects:
Chemistry
metal-metal interactions
Raman spectroscopy
X-ray diffraction
zinc
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Summary:Aminotroponiminates—very effective ligands for the stabilization of low‐valent ZnI–ZnI bonded compounds (see scheme). For the first time a stretching motion of the ZnZn bond, which is almost uncoupled to other vibrations, was found in the Raman spectrum.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201002443