Facile Catalytic Hydrosilylation of Pyridines

Not only surprisingly facile, a hydrosilylation of pyridines under the catalysis of [Cp(iPr3P)Ru(NCCH3)2]+ has the advantages that it is 1,4‐regioselective and reversible. The products can be transformed in a variety of ways (see scheme). The related complex [CpRu(NCCH3)3]+ catalyzes the two‐hydroge...

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Bibliographic Details
Published in:Angewandte Chemie (International ed.) 2011-02, Vol.50 (6), p.1384-1387
Main Authors: Gutsulyak, Dmitry V, van der Est, Art, Nikonov, Georgii I
Format: Article
Language:English
Subjects:
chemoselectivity
heterocycles
hydrosilylation
ruthenium
zinc
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Summary:Not only surprisingly facile, a hydrosilylation of pyridines under the catalysis of [Cp(iPr3P)Ru(NCCH3)2]+ has the advantages that it is 1,4‐regioselective and reversible. The products can be transformed in a variety of ways (see scheme). The related complex [CpRu(NCCH3)3]+ catalyzes the two‐hydrogen‐atom reduction of phenanthroline by HSiMe2Ph/water.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201006135