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Synthesis of graphene oxide-intercalated a-hydroxides by metathesis and their decomposition to graphene/metal oxide composites
Graphene oxide-intercalated a-metal hydroxides were prepared using layers from the delaminated colloidal dispersions of cetyltrimethylammonium-intercalated graphene oxide and dodecylsulfate-intercalated a-hydroxide of nickel/cobalt as precursors. The reaction of the two dispersions leads to de-inter...
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Published in: | Carbon (New York) 2010-12, Vol.48 (15), p.4343-4350 |
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creator | Nethravathi, C Rajamathi, Michael Ravishankar, N Basit, Lubna Felser, Claudia |
description | Graphene oxide-intercalated a-metal hydroxides were prepared using layers from the delaminated colloidal dispersions of cetyltrimethylammonium-intercalated graphene oxide and dodecylsulfate-intercalated a-hydroxide of nickel/cobalt as precursors. The reaction of the two dispersions leads to de-intercalation of the interlayer ions from both the layered solids and the intercalation of the negatively charged graphene oxide sheets between the positively charged layers of the a-hydroxide. Thermal decomposition of the intercalated solids yields graphene/nanocrystalline metal oxide composites. Electron microscopy analysis of the composites indicates that the nanoparticles are intercalated between graphene layers. |
doi_str_mv | 10.1016/j.carbon.2010.07.047 |
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The reaction of the two dispersions leads to de-intercalation of the interlayer ions from both the layered solids and the intercalation of the negatively charged graphene oxide sheets between the positively charged layers of the a-hydroxide. Thermal decomposition of the intercalated solids yields graphene/nanocrystalline metal oxide composites. Electron microscopy analysis of the composites indicates that the nanoparticles are intercalated between graphene layers.</abstract><doi>10.1016/j.carbon.2010.07.047</doi></addata></record> |
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subjects | Carbon Charging Decomposition reactions Dispersions Graphene Metal oxides Nickel Oxides |
title | Synthesis of graphene oxide-intercalated a-hydroxides by metathesis and their decomposition to graphene/metal oxide composites |
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