Solid-state thermochromism observed in charge-transfer complex composed of binaphthol and viologen

Charge-transfer complexes composed of 1,1′-bi-2-naphthol as an electron donor and viologen derivatives as electron acceptors exhibit thermochromic properties in the solid state without dramatical isomerization of the component molecules such as proton transfer.

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Bibliographic Details
Published in:Journal of molecular structure 2010-10, Vol.982 (1), p.45-49
Main Authors: Kinuta, Takafumi, Sato, Tomohiro, Tajima, Nobuo, Kuroda, Reiko, Matsubara, Yoshio, Imai, Yoshitane
Format: Article
Language:English
Subjects:
1,1′-Bi-2-naphthol
Charge-transfer complex
Crystal-engineering
Derivatives
Thermochromism
Viologen
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Description
Summary:Charge-transfer complexes composed of 1,1′-bi-2-naphthol as an electron donor and viologen derivatives as electron acceptors exhibit thermochromic properties in the solid state without dramatical isomerization of the component molecules such as proton transfer.
ISSN:0022-2860
1872-8014
DOI:10.1016/j.molstruc.2010.07.048