Nickel-catalyzed intermolecular codimerization of acrylates and alkynes

The linear codimerization of acrylates and alkynes to produce 1,3-dienes is successfully demonstrated using a nickel catalyst in association with 2-aminopyridine as an additive.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2011-01, Vol.47 (9), p.2658-2660
Main Authors: Horie, Hiroaki, Koyama, Ichiro, Kurahashi, Takuya, Matsubara, Seijiro
Format: Article
Language:English
Subjects:
Acrylates
Additives
Alkynes
Catalysts
Nickel
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Description
Summary:The linear codimerization of acrylates and alkynes to produce 1,3-dienes is successfully demonstrated using a nickel catalyst in association with 2-aminopyridine as an additive.
ISSN:1359-7345
1364-548X
DOI:10.1039/c0cc04061d