Rhodium-Catalyzed Direct Addition of Aryl CH Bonds to N-Sulfonyl Aldimines

A mild mannered reaction: An ideal addition of “inert” aryl CH bonds to CN groups has been achieved in the absence of any additives and without any undesirable by‐products (see scheme). The reaction can be carried out under mild conditions without the requirement of special techniques. Cp*=pentame...

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Bibliographic Details
Published in:Angewandte Chemie (International ed.) 2011-02, Vol.50 (9), p.2115-2119
Main Authors: Li, Yang, Li, Bi-Jie, Wang, Wen-Hua, Huang, Wei-Ping, Zhang, Xi-Sha, Chen, Kang, Shi, Zhang-Jie
Format: Article
Language:English
Subjects:
addition reactions
catalysis
CH activation
rhodium
sulfonyl aldimines
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Summary:A mild mannered reaction: An ideal addition of “inert” aryl CH bonds to CN groups has been achieved in the absence of any additives and without any undesirable by‐products (see scheme). The reaction can be carried out under mild conditions without the requirement of special techniques. Cp*=pentamethylcyclopentadienyl.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201007464