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Hollow fiber-based liquid phase microextraction (HF-LPME) for a highly sensitive HPLC determination of sulfonamides and their main metabolites
In this paper, three phase-hollow fiber-based liquid phase microextraction (HF-LPME) combined with a HPLC procedure using diode array (DAD) and fluorescence detection (FLD) has been developed for the determination of four widely used sulfonamides: sulfadiazine, sulfamerazine, sulfamethazine, sulfame...
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| Published in: | Journal of chromatography. B, Analytical technologies in the biomedical and life sciences Analytical technologies in the biomedical and life sciences, 2011-01, Vol.879 (2), p.197-204 |
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| cited_by | cdi_FETCH-LOGICAL-c479t-2a88d6945eb053344e1edb548f797dd29851eaf561345cff21c11fe63f5627a83 |
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| cites | cdi_FETCH-LOGICAL-c479t-2a88d6945eb053344e1edb548f797dd29851eaf561345cff21c11fe63f5627a83 |
| container_end_page | 204 |
| container_issue | 2 |
| container_start_page | 197 |
| container_title | Journal of chromatography. B, Analytical technologies in the biomedical and life sciences |
| container_volume | 879 |
| creator | Ramos Payán, María López, Miguel Ángel Bello Fernández-Torres, Rut Navarro, Mercedes Villar Mochón, Manuel Callejón |
| description | In this paper, three phase-hollow fiber-based liquid phase microextraction (HF-LPME) combined with a HPLC procedure using diode array (DAD) and fluorescence detection (FLD) has been developed for the determination of four widely used sulfonamides: sulfadiazine, sulfamerazine, sulfamethazine, sulfamethoxazole and their main metabolites, the corresponding N4-acetyl derivatives: N4-acetyl-sulfadiazine, N4-acetyl-sulfamerazine, N4-acetyl-sulfamethazine, N4-acetyl-sulfamethoxazole. A Q3/2 Accurel KM polypropylene hollow fiber supporting 1-octanol was used between a 2M Na2SO4 aqueous solution (pH 4) as a donor phase and aqueous solution (pH 12) as an acceptor phase. The procedure allows very low detection and quantitation limits of 0.3–33ngL−1 and 0.9–100ngL−1, respectively. The proposed method was applied to the determination of the analytes in environmental water samples (surface, tap and wastewater). |
| doi_str_mv | 10.1016/j.jchromb.2010.12.006 |
| format | article |
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A Q3/2 Accurel KM polypropylene hollow fiber supporting 1-octanol was used between a 2M Na2SO4 aqueous solution (pH 4) as a donor phase and aqueous solution (pH 12) as an acceptor phase. The procedure allows very low detection and quantitation limits of 0.3–33ngL−1 and 0.9–100ngL−1, respectively. 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Psychology ; General pharmacology ; Hafnium ; HF-LPME ; high performance liquid chromatography ; Hollow fiber liquid phase microextraction ; HPLC ; Least-Squares Analysis ; Liquid phases ; liquid-phase microextraction ; Medical sciences ; Metabolites ; Pharmacology. Drug treatments ; Polypropylenes ; Reproducibility of Results ; Rivers - chemistry ; sodium sulfate ; sulfadiazine ; sulfamerazine ; sulfamethoxazole ; Sulfonamides ; Sulfonamides - analysis ; Sulfonamides - chemistry ; surface water ; Waste water ; wastewater ; Water Pollutants, Chemical - analysis ; Water Pollutants, Chemical - chemistry</subject><ispartof>Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 2011-01, Vol.879 (2), p.197-204</ispartof><rights>2010 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><rights>Copyright © 2010 Elsevier B.V. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c479t-2a88d6945eb053344e1edb548f797dd29851eaf561345cff21c11fe63f5627a83</citedby><cites>FETCH-LOGICAL-c479t-2a88d6945eb053344e1edb548f797dd29851eaf561345cff21c11fe63f5627a83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23750833$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21185241$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ramos Payán, María</creatorcontrib><creatorcontrib>López, Miguel Ángel Bello</creatorcontrib><creatorcontrib>Fernández-Torres, Rut</creatorcontrib><creatorcontrib>Navarro, Mercedes Villar</creatorcontrib><creatorcontrib>Mochón, Manuel Callejón</creatorcontrib><title>Hollow fiber-based liquid phase microextraction (HF-LPME) for a highly sensitive HPLC determination of sulfonamides and their main metabolites</title><title>Journal of chromatography. B, Analytical technologies in the biomedical and life sciences</title><addtitle>J Chromatogr B Analyt Technol Biomed Life Sci</addtitle><description>In this paper, three phase-hollow fiber-based liquid phase microextraction (HF-LPME) combined with a HPLC procedure using diode array (DAD) and fluorescence detection (FLD) has been developed for the determination of four widely used sulfonamides: sulfadiazine, sulfamerazine, sulfamethazine, sulfamethoxazole and their main metabolites, the corresponding N4-acetyl derivatives: N4-acetyl-sulfadiazine, N4-acetyl-sulfamerazine, N4-acetyl-sulfamethazine, N4-acetyl-sulfamethoxazole. A Q3/2 Accurel KM polypropylene hollow fiber supporting 1-octanol was used between a 2M Na2SO4 aqueous solution (pH 4) as a donor phase and aqueous solution (pH 12) as an acceptor phase. The procedure allows very low detection and quantitation limits of 0.3–33ngL−1 and 0.9–100ngL−1, respectively. The proposed method was applied to the determination of the analytes in environmental water samples (surface, tap and wastewater).</description><subject>Analysis</subject><subject>Analytical, structural and metabolic biochemistry</subject><subject>Aqueous solutions</subject><subject>Arrays</subject><subject>Biological and medical sciences</subject><subject>Chemical Fractionation - methods</subject><subject>Chromatography, High Pressure Liquid - methods</subject><subject>Derivatives</subject><subject>drinking water</subject><subject>drug residues</subject><subject>Environmental water</subject><subject>fluorescence</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>General pharmacology</subject><subject>Hafnium</subject><subject>HF-LPME</subject><subject>high performance liquid chromatography</subject><subject>Hollow fiber liquid phase microextraction</subject><subject>HPLC</subject><subject>Least-Squares Analysis</subject><subject>Liquid phases</subject><subject>liquid-phase microextraction</subject><subject>Medical sciences</subject><subject>Metabolites</subject><subject>Pharmacology. Drug treatments</subject><subject>Polypropylenes</subject><subject>Reproducibility of Results</subject><subject>Rivers - chemistry</subject><subject>sodium sulfate</subject><subject>sulfadiazine</subject><subject>sulfamerazine</subject><subject>sulfamethoxazole</subject><subject>Sulfonamides</subject><subject>Sulfonamides - analysis</subject><subject>Sulfonamides - chemistry</subject><subject>surface water</subject><subject>Waste water</subject><subject>wastewater</subject><subject>Water Pollutants, Chemical - analysis</subject><subject>Water Pollutants, Chemical - chemistry</subject><issn>1570-0232</issn><issn>1873-376X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkc9u1DAQhyMEoqXwCIAvCDhk8Z84Tk4IrVoWaRGVoBI3y7HHXa-ceGs7hb4Ez4yXXeDYk-3R9_OM5quq5wQvCCbtu-1iqzcxjMOC4n2NLjBuH1SnpBOsZqL9_rDcucA1poyeVE9S2mJMBBbscXVCCek4bchp9WsVvA8_kHUDxHpQCQzy7mZ2Bu025YVGp2OAnzkqnV2Y0JvVRb2-_Hz-FtkQkUIbd73xdyjBlFx2t4BWl-slMpAhjm5SfzLBojR7GyY1OgMJqcmgvAEX0ajchEbIagjeZUhPq0dW-QTPjudZdXVx_m25qtdfPn5afljXuhF9rqnqOtP2DYcBc8aaBgiYgTedFb0whvYdJ6AsbwlruLaWEk2IhZaVEhWqY2fV68O_uxhuZkhZji5p8F5NEOYkO84Fobhp7ycb1hDKe1xIfiDLwlKKYOUuulHFO0mw3DuTW3l0JvfOJKGyOCu5F8cO8zCC-Zf6K6kAr46ASlp5G9WkXfrPMcFxx1jhXh44q4JU17EwV19LJ44xFi3hvBDvDwSU3d46iDJpB5MG4yLoLE1w9wz7G98YwW0</recordid><startdate>20110115</startdate><enddate>20110115</enddate><creator>Ramos Payán, María</creator><creator>López, Miguel Ángel Bello</creator><creator>Fernández-Torres, Rut</creator><creator>Navarro, Mercedes Villar</creator><creator>Mochón, Manuel Callejón</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>FBQ</scope><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7TB</scope><scope>8FD</scope><scope>FR3</scope></search><sort><creationdate>20110115</creationdate><title>Hollow fiber-based liquid phase microextraction (HF-LPME) for a highly sensitive HPLC determination of sulfonamides and their main metabolites</title><author>Ramos Payán, María ; López, Miguel Ángel Bello ; Fernández-Torres, Rut ; Navarro, Mercedes Villar ; Mochón, Manuel Callejón</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c479t-2a88d6945eb053344e1edb548f797dd29851eaf561345cff21c11fe63f5627a83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Analysis</topic><topic>Analytical, structural and metabolic biochemistry</topic><topic>Aqueous solutions</topic><topic>Arrays</topic><topic>Biological and medical sciences</topic><topic>Chemical Fractionation - methods</topic><topic>Chromatography, High Pressure Liquid - methods</topic><topic>Derivatives</topic><topic>drinking water</topic><topic>drug residues</topic><topic>Environmental water</topic><topic>fluorescence</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>General pharmacology</topic><topic>Hafnium</topic><topic>HF-LPME</topic><topic>high performance liquid chromatography</topic><topic>Hollow fiber liquid phase microextraction</topic><topic>HPLC</topic><topic>Least-Squares Analysis</topic><topic>Liquid phases</topic><topic>liquid-phase microextraction</topic><topic>Medical sciences</topic><topic>Metabolites</topic><topic>Pharmacology. Drug treatments</topic><topic>Polypropylenes</topic><topic>Reproducibility of Results</topic><topic>Rivers - chemistry</topic><topic>sodium sulfate</topic><topic>sulfadiazine</topic><topic>sulfamerazine</topic><topic>sulfamethoxazole</topic><topic>Sulfonamides</topic><topic>Sulfonamides - analysis</topic><topic>Sulfonamides - chemistry</topic><topic>surface water</topic><topic>Waste water</topic><topic>wastewater</topic><topic>Water Pollutants, Chemical - analysis</topic><topic>Water Pollutants, Chemical - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ramos Payán, María</creatorcontrib><creatorcontrib>López, Miguel Ángel Bello</creatorcontrib><creatorcontrib>Fernández-Torres, Rut</creatorcontrib><creatorcontrib>Navarro, Mercedes Villar</creatorcontrib><creatorcontrib>Mochón, Manuel Callejón</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><jtitle>Journal of chromatography. 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B, Analytical technologies in the biomedical and life sciences</jtitle><addtitle>J Chromatogr B Analyt Technol Biomed Life Sci</addtitle><date>2011-01-15</date><risdate>2011</risdate><volume>879</volume><issue>2</issue><spage>197</spage><epage>204</epage><pages>197-204</pages><issn>1570-0232</issn><eissn>1873-376X</eissn><abstract>In this paper, three phase-hollow fiber-based liquid phase microextraction (HF-LPME) combined with a HPLC procedure using diode array (DAD) and fluorescence detection (FLD) has been developed for the determination of four widely used sulfonamides: sulfadiazine, sulfamerazine, sulfamethazine, sulfamethoxazole and their main metabolites, the corresponding N4-acetyl derivatives: N4-acetyl-sulfadiazine, N4-acetyl-sulfamerazine, N4-acetyl-sulfamethazine, N4-acetyl-sulfamethoxazole. A Q3/2 Accurel KM polypropylene hollow fiber supporting 1-octanol was used between a 2M Na2SO4 aqueous solution (pH 4) as a donor phase and aqueous solution (pH 12) as an acceptor phase. The procedure allows very low detection and quantitation limits of 0.3–33ngL−1 and 0.9–100ngL−1, respectively. The proposed method was applied to the determination of the analytes in environmental water samples (surface, tap and wastewater).</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><pmid>21185241</pmid><doi>10.1016/j.jchromb.2010.12.006</doi><tpages>8</tpages></addata></record> |
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| identifier | ISSN: 1570-0232 |
| ispartof | Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 2011-01, Vol.879 (2), p.197-204 |
| issn | 1570-0232 1873-376X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_855712046 |
| source | Elsevier |
| subjects | Analysis Analytical, structural and metabolic biochemistry Aqueous solutions Arrays Biological and medical sciences Chemical Fractionation - methods Chromatography, High Pressure Liquid - methods Derivatives drinking water drug residues Environmental water fluorescence Fundamental and applied biological sciences. Psychology General pharmacology Hafnium HF-LPME high performance liquid chromatography Hollow fiber liquid phase microextraction HPLC Least-Squares Analysis Liquid phases liquid-phase microextraction Medical sciences Metabolites Pharmacology. Drug treatments Polypropylenes Reproducibility of Results Rivers - chemistry sodium sulfate sulfadiazine sulfamerazine sulfamethoxazole Sulfonamides Sulfonamides - analysis Sulfonamides - chemistry surface water Waste water wastewater Water Pollutants, Chemical - analysis Water Pollutants, Chemical - chemistry |
| title | Hollow fiber-based liquid phase microextraction (HF-LPME) for a highly sensitive HPLC determination of sulfonamides and their main metabolites |
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