Grafting of p-styrene sulfonate and 1,3-propane sultone onto Laponite for proton exchange membrane fuel cell application

• Published in: Journal of membrane science 2011, Vol.366 (1), p.33-42
• Main Authors: Fatyeyeva, Kateryna, Bigarré, Janick, Blondel, Benoit, Galiano, Hervé, Gaud, David, Lecardeur, Magali, Poncin-Epaillard, Fabienne
• Format: Article
• Language: English
• Subjects: Applied sciences; artificial membranes; cation exchange; chemical structure; Chemistry; clay; Colloidal state and disperse state; Energy; Energy. Thermal use of fuels; Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc; Exact sciences and technology; Fourier transform infrared spectroscopy; Fuel cells; General and physical chemistry; Grafting; Hybrid nanocomposite; Laponite; Membranes; nanocomposites; Plasma; Proton exchange membrane fuel cell; styrene; sulfonates; surfaces; thermal analysis; thermal stability; X-ray diffraction; X-ray photoelectron spectroscopy
• ISSN: 0376-7388; 1873-3123
• DOI: 10.1016/j.memsci.2010.09.023

. [Display omitted] ▶ Two proton conductive groups, p-styrene sulfonic acid and 1,3-propane sultone, have been bonded to the Laponite surface. ▶ The maximum sulfur content depends on the various parameters (such as plasma and grafting conditions). ▶ The fuel cell performance with hybrid membranes is better than that with the pure Nafion ® membrane. Chemical modification of clay (Laponite) particles was carried out through the plasma activation process and chemical grafting of sulfonic groups. The occurrence of the surface modification and the chemical structure of resulting products were characterized with FTIR, XPS and thermal analysis. Also, X-ray diffraction spectrometry observation of the Laponite particles confirmed the surface modification. Proposed approach provides the original method of organically modified clay particles and can be applied to the preparation of hybrid organic–inorganic nanocomposites. The application of Nafion ®/modified Laponite hybrid membranes for proton exchange membrane fuel cells was evaluated in terms of proton conductivity, swelling degree and cell performance. By increasing the proton conductivity of the Laponite and the thermal stability of the composite membrane, the performance of fuel cell made with this type of membrane was improved.