On the directionality of anion-π interactions

The directionality of two important noncovalent interactions involving aromatic rings (namely anion-π and cation-π) is investigated. It has been recently published that the anion-π interactions observed in X-ray structures where the anion is located exactly over the center of the ring are scarce com...

Full description

Saved in:
Bibliographic Details
Published in:Physical chemistry chemical physics : PCCP 2011-04, Vol.13 (13), p.5696-5702
Main Authors: ESTARELLAS, Carolina, BAUZA, Antonio, FRONTERA, Antonio, QUINONERO, David, DEYA, Pere M
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
General and physical chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The directionality of two important noncovalent interactions involving aromatic rings (namely anion-π and cation-π) is investigated. It has been recently published that the anion-π interactions observed in X-ray structures where the anion is located exactly over the center of the ring are scarce compared to cation-π interactions. To explain this behavior, we have analyzed how the interaction energy (RI-MP2/aug-cc-pVDZ level of theory) is affected by moving the anion from the center of the ring to several directions in anion-π complexes of chloride with either hexafluorobenzene or trifluoro-s-triazine. We have compared the results with the directionality of the cation-π interaction in the sodium-benzene complex. The results are useful to explain the experimental differences between both ion-π interactions. We have also computed the van der Waals radii of several halide anions and we have compared them to the neutral halogen atoms.
ISSN:1463-9076
1463-9084
DOI:10.1039/c0cp01894e