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A quadruply-bonded [Cr2(guanidinate)4]4- tetraanion

The reaction of chromocene, Cp(2)Cr, with dilithiated 2,3-diphenylguanidine [(PhNH)(2)C=NH = L(2)H(3)] gives the novel, quadruply-bonded tetraanion [Cr(2)(L(2)H)(4)](4-).

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2011-04, Vol.47 (14), p.4120-4122
Main Authors: Haywood, Joanna, Stokes, Francesca A, Less, Robert J, McPartlin, Mary, Wheatley, Andrew E H, Wright, Dominic S
Format: Article
Language:English
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Summary:The reaction of chromocene, Cp(2)Cr, with dilithiated 2,3-diphenylguanidine [(PhNH)(2)C=NH = L(2)H(3)] gives the novel, quadruply-bonded tetraanion [Cr(2)(L(2)H)(4)](4-).
ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc10194c