New Microporous Metal−Organic Framework Demonstrating Unique Selectivity for Detection of High Explosives and Aromatic Compounds

A highly luminescent three-dimensional microporous metal−organic framework, [Zn2(oba)2(bpy)]·DMA, demonstrates unique selectivity for the detection of high explosives and other aromatics via a fluorescence quenching and enhancement mechanism.

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Bibliographic Details
Published in:Journal of the American Chemical Society 2011-03, Vol.133 (12), p.4153-4155
Main Authors: Pramanik, Sanhita, Zheng, Chong, Zhang, Xiao, Emge, Thomas J, Li, Jing
Format: Article
Language:English
Subjects:
Explosive Agents - analysis
Explosive Agents - chemistry
Hydrocarbons, Aromatic - analysis
Hydrocarbons, Aromatic - chemistry
Luminescence
Models, Molecular
Organometallic Compounds - analysis
Organometallic Compounds - chemistry
Particle Size
Porosity
Surface Properties
Zinc - chemistry
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Description
Summary:A highly luminescent three-dimensional microporous metal−organic framework, [Zn2(oba)2(bpy)]·DMA, demonstrates unique selectivity for the detection of high explosives and other aromatics via a fluorescence quenching and enhancement mechanism.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja106851d