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CuI-Nanoparticles-Catalyzed Selective Synthesis of Phenols, Anilines, and Thiophenols from Aryl Halides in Aqueous Solution

CuI-nanoparticles-catalyzed selective synthesis of phenols, anilines, and thiophenols from aryl halides was developed in the absence of both ligands and organic solvents. Anilines were formed selectively with ammonia competing with hydroxylation and thiophenols were generated selectively with sulfur...

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Published in:Journal of organic chemistry 2011-04, Vol.76 (7), p.2296-2300
Main Authors: Xu, Hua-Jian, Liang, Yu-Feng, Cai, Zhen-Ya, Qi, Hong-Xia, Yang, Chun-Yan, Feng, Yi-Si
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cited_by cdi_FETCH-LOGICAL-a295t-6df003ac08c771a7d17bb54446e1f3782ffd6996dd6aa3551c9716dba19a76ae3
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description CuI-nanoparticles-catalyzed selective synthesis of phenols, anilines, and thiophenols from aryl halides was developed in the absence of both ligands and organic solvents. Anilines were formed selectively with ammonia competing with hydroxylation and thiophenols were generated selectively with sulfur powder after subsequent reduction competing with hydroxylation and amination.
doi_str_mv 10.1021/jo102506x
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source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Aniline Compounds - chemical synthesis
Aniline Compounds - chemistry
Catalysis
Copper - chemistry
Hydrocarbons, Halogenated - chemistry
Iodides - chemistry
Ligands
Molecular Structure
Nanoparticles - chemistry
Phenols - chemical synthesis
Phenols - chemistry
Solutions - chemistry
Solvents - chemistry
Sulfhydryl Compounds - chemical synthesis
Sulfhydryl Compounds - chemistry
title CuI-Nanoparticles-Catalyzed Selective Synthesis of Phenols, Anilines, and Thiophenols from Aryl Halides in Aqueous Solution
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