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CuI-Nanoparticles-Catalyzed Selective Synthesis of Phenols, Anilines, and Thiophenols from Aryl Halides in Aqueous Solution
CuI-nanoparticles-catalyzed selective synthesis of phenols, anilines, and thiophenols from aryl halides was developed in the absence of both ligands and organic solvents. Anilines were formed selectively with ammonia competing with hydroxylation and thiophenols were generated selectively with sulfur...
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Published in: | Journal of organic chemistry 2011-04, Vol.76 (7), p.2296-2300 |
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container_end_page | 2300 |
container_issue | 7 |
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container_title | Journal of organic chemistry |
container_volume | 76 |
creator | Xu, Hua-Jian Liang, Yu-Feng Cai, Zhen-Ya Qi, Hong-Xia Yang, Chun-Yan Feng, Yi-Si |
description | CuI-nanoparticles-catalyzed selective synthesis of phenols, anilines, and thiophenols from aryl halides was developed in the absence of both ligands and organic solvents. Anilines were formed selectively with ammonia competing with hydroxylation and thiophenols were generated selectively with sulfur powder after subsequent reduction competing with hydroxylation and amination. |
doi_str_mv | 10.1021/jo102506x |
format | article |
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source | American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list) |
subjects | Aniline Compounds - chemical synthesis Aniline Compounds - chemistry Catalysis Copper - chemistry Hydrocarbons, Halogenated - chemistry Iodides - chemistry Ligands Molecular Structure Nanoparticles - chemistry Phenols - chemical synthesis Phenols - chemistry Solutions - chemistry Solvents - chemistry Sulfhydryl Compounds - chemical synthesis Sulfhydryl Compounds - chemistry |
title | CuI-Nanoparticles-Catalyzed Selective Synthesis of Phenols, Anilines, and Thiophenols from Aryl Halides in Aqueous Solution |
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