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Fluorescent Phosphane Selenide As Efficient Mercury Chemodosimeter
The synthesis and photophysical properties of a novel fluorescent sensor are described. The phosphorus−selenium moiety allowed a selective mercury salt complexation, followed by the formation of phosphane oxide, which leads to a turn-on of the fluorescence. The sensibility and selectivity toward mer...
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Published in: | Organic letters 2011-03, Vol.13 (5), p.1182-1185 |
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container_title | Organic letters |
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creator | Samb, Issa Bell, Jérémy Toullec, Patrick Y Michelet, Véronique Leray, Isabelle |
description | The synthesis and photophysical properties of a novel fluorescent sensor are described. The phosphorus−selenium moiety allowed a selective mercury salt complexation, followed by the formation of phosphane oxide, which leads to a turn-on of the fluorescence. The sensibility and selectivity toward mercury cations were evaluated (0.18 ppb) and found to be in complete adequation with the targeted level of the World Health Organization, which makes the dye an efficient dosimeter for mercury cations. |
doi_str_mv | 10.1021/ol200066p |
format | article |
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source | American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list) |
subjects | Environmental Pollutants - analysis Fluorescent Dyes - chemical synthesis Fluorescent Dyes - chemistry Mercury - analysis Molecular Structure Organoselenium Compounds - chemical synthesis Organoselenium Compounds - chemistry Phosphines - chemical synthesis Phosphines - chemistry World Health Organization |
title | Fluorescent Phosphane Selenide As Efficient Mercury Chemodosimeter |
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