A new cataluminescence gas sensor based on SiO2 nanotubes fabricated using carbon nanotube templates

• Published in: Talanta (Oxford) 2011-05, Vol.84 (3), p.977-982
• Main Authors: Wang, Yali, Cao, Xiaoan, Li, Jinwen, Chen, Nan
• Format: Article
• Language: English
• Subjects: Analytical chemistry; Chemistry; Exact sciences and technology; General, instrumentation
• ISSN: 0039-9140; 1873-3573
• DOI: 10.1016/j.talanta.2011.02.047

In the present work, two morphologies of SiO(2) nanomaterials (SiO(2) nanotubes and nanoparticles) have been successfully synthesized in supercritical fluids (SCFs). The cataluminescence (CTL) features of the two SiO(2) nanomaterials to some common harmful gases were compared, and the results showed that SiO(2) nanotubes had better CTL sensing characteristic to some common harmful gases. The SiO(2) nanotubes not only had uniform size and shape with a high specific surface area, but also exhibited superior sensitivity and selectivity to ethyl acetate vapor. Using the SiO(2) nanotubes as sensing material, a CTL sensor for ethyl acetate vapor was developed. The proposed sensor showed high sensitivity and specificity to ethyl acetate at optimal temperature of 293°C, a wavelength of 425 nm and a flow rate of 345 mL/min. With a detection limit of 0.85 ppm, the linear range of CTL intensity versus concentrations of ethyl acetate vapor was 2.0-2000 ppm. None or only very low levels of interference were observed while the foreign substances such as acetone, acetaldehyde, acetic acid, formaldehyde, ammonia, ethanol, benzene and methanol were passing through the sensor. This method allows rapid determination of gaseous ethyl acetate at workshop.