Carbonyl Complexes of Platinum(0): Synthesis and Structure of [(Cy3P)2Pt(CO)] and [(Cy3P)2Pt(CO)2]

The platinum(0) monocarbonyl complex, [(Cy3P)2Pt(CO)], was synthesized by reaction of [(Cy3P)2Pt] with [(η5-C5Me5)Ir(CO)2] and subsequent irradiation. X-ray structure analysis was performed and represents the first structural evidence of a platinum(0) monocarbonyl complex bearing two free phosphine...

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Bibliographic Details
Published in:Inorganic chemistry 2011-03, Vol.50 (5), p.1816-1819
Main Authors: Bertsch, Stefanie, Braunschweig, Holger, Forster, Melanie, Gruss, Katrin, Radacki, Krzysztof
Format: Article
Language:English
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Summary:The platinum(0) monocarbonyl complex, [(Cy3P)2Pt(CO)], was synthesized by reaction of [(Cy3P)2Pt] with [(η5-C5Me5)Ir(CO)2] and subsequent irradiation. X-ray structure analysis was performed and represents the first structural evidence of a platinum(0) monocarbonyl complex bearing two free phosphine ligands. Its corresponding dicarbonyl complex [(Cy3P)2Pt(CO)2] was synthesized by treatment of [(Cy3P)2Pt] with CO at −40 °C and confirmed by X-ray structure analysis.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic102200t