Assembly and Manipulation of Rotatable Cerium Porphyrinato Sandwich Complexes on a Surface

Stacked up: Use of scanning tunneling microscopy allows manipulation of the upper porphyrin of tris(porphyrinato) cerium triple‐decker complexes, which are obtained by a new synthetic route on a smooth Ag(111) surface (see picture).

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2011-04, Vol.50 (17), p.3872-3877
Main Authors: Écija, David, Auwärter, Willi, Vijayaraghavan, Saranyan, Seufert, Knud, Bischoff, Felix, Tashiro, Kentaro, Barth, Johannes V.
Format: Article
Language:English
Subjects:
Cerium
molecular rotors
nanochemistry
porphyrins
scanning probe microscopy
self-assembly
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Description
Summary:Stacked up: Use of scanning tunneling microscopy allows manipulation of the upper porphyrin of tris(porphyrinato) cerium triple‐decker complexes, which are obtained by a new synthetic route on a smooth Ag(111) surface (see picture).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201007370