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The effects of exposure in space on two high-performance polymers
Films of a polyimide, poly(pyromellitimide-1,4-diphenyl ether), and a poly(etherimide), commercial Ultem ®, both pure and with additives were exposed to the low earth orbit (LEO) space environment on several missions of the Materials on the International Space Station Experiment (MISSE). The additiv...
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| Published in: | Radiation physics and chemistry (Oxford, England : 1993) England : 1993), 2011-02, Vol.80 (2), p.126-129 |
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| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c353t-83f9442081052b074e264bc5f91f2e19a5e937136eeefafe9de02ef86b96c22b3 |
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| cites | cdi_FETCH-LOGICAL-c353t-83f9442081052b074e264bc5f91f2e19a5e937136eeefafe9de02ef86b96c22b3 |
| container_end_page | 129 |
| container_issue | 2 |
| container_start_page | 126 |
| container_title | Radiation physics and chemistry (Oxford, England : 1993) |
| container_volume | 80 |
| creator | Kiefer, Richard L. Gabler, William J. Hovey, Michael T. Thibeault, Sheila A. |
| description | Films of a polyimide, poly(pyromellitimide-1,4-diphenyl ether), and a poly(etherimide), commercial Ultem
®, both pure and with additives were exposed to the low earth orbit (LEO) space environment on several missions of the Materials on the International Space Station Experiment (MISSE). The additives, which contained aluminum or boron, were designed to interact with atomic oxygen to form a protective metal oxide coating. A polyimide film containing 10% aluminum acetylacetonate (Al(acac)
3) survived an exposure of nearly four year while an adjacent pure film was completely eroded.
After exposure in space, films containing aluminum showed an enhanced amount of the element on the surface along with an enhanced amount of oxygen. Boron-containing films showed no enhancement of the element after exposure. The temperature of 10% mass loss increased with space exposure for films containing aluminum but decreased for those containing boron. The glass transition temperature (
T
g) increased after space exposure for polyimide films containing Al(acac)
3. |
| doi_str_mv | 10.1016/j.radphyschem.2010.07.019 |
| format | article |
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®, both pure and with additives were exposed to the low earth orbit (LEO) space environment on several missions of the Materials on the International Space Station Experiment (MISSE). The additives, which contained aluminum or boron, were designed to interact with atomic oxygen to form a protective metal oxide coating. A polyimide film containing 10% aluminum acetylacetonate (Al(acac)
3) survived an exposure of nearly four year while an adjacent pure film was completely eroded.
After exposure in space, films containing aluminum showed an enhanced amount of the element on the surface along with an enhanced amount of oxygen. Boron-containing films showed no enhancement of the element after exposure. The temperature of 10% mass loss increased with space exposure for films containing aluminum but decreased for those containing boron. The glass transition temperature (
T
g) increased after space exposure for polyimide films containing Al(acac)
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3) survived an exposure of nearly four year while an adjacent pure film was completely eroded.
After exposure in space, films containing aluminum showed an enhanced amount of the element on the surface along with an enhanced amount of oxygen. Boron-containing films showed no enhancement of the element after exposure. The temperature of 10% mass loss increased with space exposure for films containing aluminum but decreased for those containing boron. The glass transition temperature (
T
g) increased after space exposure for polyimide films containing Al(acac)
3.</description><subject>Aluminum</subject><subject>Atomic oxygen</subject><subject>Boron</subject><subject>Ethers</subject><subject>Metal oxides</subject><subject>MISSE</subject><subject>Poly(etherimide)</subject><subject>Polyetherimides</subject><subject>Polyimide</subject><subject>Polyimide resins</subject><subject>Space environment</subject><issn>0969-806X</issn><issn>1879-0895</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqNkE1LxDAYhIMouK7-h3jy1PqmadPkuCx-geBlBW-hTd_YLm1Tk666_94s68Gjp4FhZmAeQq4ZpAyYuN2mvmqmdh9Mi0OaQfShTIGpE7JgslQJSFWckgUooRIJ4u2cXISwBYBSFnxBVpsWKVqLZg7UWYrfkws7j7QbaZgqg9SNdP5ytO3e22RCb50fqjH6k-v3A_pwSc5s1Qe8-tUleb2_26wfk-eXh6f16jkxvOBzIrlVeZ6BZFBkNZQ5ZiKvTWEVsxkyVRWoeMm4QERbWVQNQoZWiloJk2U1X5Kb4-7k3ccOw6yHLhjs-2pEtwtaipxLpYDHpDomjXcheLR68t1Q-b1moA_U9Fb_oaYP1DSUOlKL3fWxi_HKZ4deB9Nh_Nt0PjLSjev-sfIDjXB8iw</recordid><startdate>20110201</startdate><enddate>20110201</enddate><creator>Kiefer, Richard L.</creator><creator>Gabler, William J.</creator><creator>Hovey, Michael T.</creator><creator>Thibeault, Sheila A.</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20110201</creationdate><title>The effects of exposure in space on two high-performance polymers</title><author>Kiefer, Richard L. ; Gabler, William J. ; Hovey, Michael T. ; Thibeault, Sheila A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-83f9442081052b074e264bc5f91f2e19a5e937136eeefafe9de02ef86b96c22b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Aluminum</topic><topic>Atomic oxygen</topic><topic>Boron</topic><topic>Ethers</topic><topic>Metal oxides</topic><topic>MISSE</topic><topic>Poly(etherimide)</topic><topic>Polyetherimides</topic><topic>Polyimide</topic><topic>Polyimide resins</topic><topic>Space environment</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kiefer, Richard L.</creatorcontrib><creatorcontrib>Gabler, William J.</creatorcontrib><creatorcontrib>Hovey, Michael T.</creatorcontrib><creatorcontrib>Thibeault, Sheila A.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Radiation physics and chemistry (Oxford, England : 1993)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kiefer, Richard L.</au><au>Gabler, William J.</au><au>Hovey, Michael T.</au><au>Thibeault, Sheila A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The effects of exposure in space on two high-performance polymers</atitle><jtitle>Radiation physics and chemistry (Oxford, England : 1993)</jtitle><date>2011-02-01</date><risdate>2011</risdate><volume>80</volume><issue>2</issue><spage>126</spage><epage>129</epage><pages>126-129</pages><issn>0969-806X</issn><eissn>1879-0895</eissn><abstract>Films of a polyimide, poly(pyromellitimide-1,4-diphenyl ether), and a poly(etherimide), commercial Ultem
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3) survived an exposure of nearly four year while an adjacent pure film was completely eroded.
After exposure in space, films containing aluminum showed an enhanced amount of the element on the surface along with an enhanced amount of oxygen. Boron-containing films showed no enhancement of the element after exposure. The temperature of 10% mass loss increased with space exposure for films containing aluminum but decreased for those containing boron. The glass transition temperature (
T
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| fulltext | fulltext |
| identifier | ISSN: 0969-806X |
| ispartof | Radiation physics and chemistry (Oxford, England : 1993), 2011-02, Vol.80 (2), p.126-129 |
| issn | 0969-806X 1879-0895 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_864389903 |
| source | ScienceDirect Freedom Collection 2022-2024 |
| subjects | Aluminum Atomic oxygen Boron Ethers Metal oxides MISSE Poly(etherimide) Polyetherimides Polyimide Polyimide resins Space environment |
| title | The effects of exposure in space on two high-performance polymers |
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