I2-doped and pyrrole ring-iodinated semi-conducting oligomers of N-vinyl-3-alkyl-2-phenylpyrroles

I2-doped and pyrrole ring-iodinated semi-conducting oligomers of N-vinyl-3-alkyl-2-phenylpyrroles have been synthesized by free-radical polymerization of the above monomers (AIBN, 2-5wt%, 60-80A degree C) and further exposure of the oligomers obtained to I2 vapor. The parent oligomers exhibit parama...

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Bibliographic Details
Published in:Synthetic metals 2010-12, Vol.160 (23-24), p.2573-2580
Main Authors: Trofimov, Boris A., Markova, Marina V., Tatarinova, Inna V., Mikhaleva, Al’bina I., Morozova, Lyudmila V., Petrova, Ol’ga V., Sobenina, Lyubov’ N., Petrushenko, Konstantin B., Vakul'skaya, Tamara I., Khutsishvili, Spartak S., Prozorova, Galina F.
Format: Article
Language:English
Subjects:
Monomers
Oligomers
Parents
Polymerization
Pyrroles
Semiconductors
Synthetic metals
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Summary:I2-doped and pyrrole ring-iodinated semi-conducting oligomers of N-vinyl-3-alkyl-2-phenylpyrroles have been synthesized by free-radical polymerization of the above monomers (AIBN, 2-5wt%, 60-80A degree C) and further exposure of the oligomers obtained to I2 vapor. The parent oligomers exhibit paramagnetic and fluorescent properties and stable up to 300-370A degree C.
ISSN:0379-6779
DOI:10.1016/j.synthmet.2010.10.007