Palladium-Catalyzed Desulfitative Heck-Type Reaction of Aryl Sulfinic Acids with Alkenes

An efficient protocol has been developed for the desulfitative Heck‐type reaction of aryl sulfinic acids with a variety of alkenes in the presence of a catalytic amount of Pd(OAc)2 and inexpensive Cu(OAc)2 as oxidant. This method does not require a ligand or a base, thereby broadening the scope of P...

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Bibliographic Details
Published in:Chemistry : a European journal 2011-05, Vol.17 (21), p.5787-5790
Main Authors: Wang, Guan-Wu, Miao, Tao
Format: Article
Language:English
Subjects:
alkenes
Alkenes - chemistry
arylation
Catalysis
Chemistry
cross-coupling
Cross-Linking Reagents - chemistry
desulfitation
Molecular Structure
palladium
Palladium - chemistry
Sulfinic Acids - chemistry
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Summary:An efficient protocol has been developed for the desulfitative Heck‐type reaction of aryl sulfinic acids with a variety of alkenes in the presence of a catalytic amount of Pd(OAc)2 and inexpensive Cu(OAc)2 as oxidant. This method does not require a ligand or a base, thereby broadening the scope of Pd‐catalyzed coupling reactions.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201100539