Highly chemoselective hydrogenation of crotonaldehyde over Ag-In/SBA-15 fabricated by a modified "two solvents" strategy

In the challenging crotonaldehyde hydrogenation to crotyl alcohol, an Ag-In/SBA-15 catalyst fabricated by a modified "two solvents" strategy shows an unprecedentedly high yield of 86% at a selectivity of 87%, which exceeds the best results on Pt-, Au- and other Ag-based heterogeneous catal...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2011-01, Vol.47 (21), p.6168-6170
Main Authors: Tian, Li, Yang, Qiuyun, Jiang, Zheng, Zhu, Yuan, Pei, Yan, Qiao, Minghua, Fan, Kangnian
Format: Article
Language:English
Subjects:
Catalysts
Gold
Hydrogenation
Platinum
Selectivity
Silver
Solvents
Strategy
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Summary:In the challenging crotonaldehyde hydrogenation to crotyl alcohol, an Ag-In/SBA-15 catalyst fabricated by a modified "two solvents" strategy shows an unprecedentedly high yield of 86% at a selectivity of 87%, which exceeds the best results on Pt-, Au- and other Ag-based heterogeneous catalysts reported so far.
ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc11013f