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Discrimination of Organic Acids Using a Three Molecule Array Based upon Cruciform Fluorophores

A small array was obtained from three reactive cruciform fluorophores in six different solvents. The array discerned 10 different aromatic carboxylic acids by protonation-induced fluorescence shifts, which were recorded by digital photography. This simple array can discern acids that have closely sp...

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Bibliographic Details
Published in:Journal of the American Chemical Society 2011-05, Vol.133 (20), p.7716-7718
Main Authors: Davey, Evan A, Zucchero, Anthony J, Trapp, Oliver, Bunz, Uwe H. F
Format: Article
Language:English
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Summary:A small array was obtained from three reactive cruciform fluorophores in six different solvents. The array discerned 10 different aromatic carboxylic acids by protonation-induced fluorescence shifts, which were recorded by digital photography. This simple array can discern acids that have closely spaced pK a values.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja202654r