Application of persulfate to remediate petroleum hydrocarbon-contaminated soil: Feasibility and comparison with common oxidants

• Published in: Journal of hazardous materials 2011-02, Vol.186 (2-3), p.2097-2102
• Main Authors: Yen, Chia-Hsien, Chen, Ku-Fan, Kao, Chih-Ming, Liang, Shu-Hao, Chen, Ting-Yu
• Format: Article
• Language: English
• Subjects: ambient temperature; anions; Applied sciences; Chemical engineering; Contaminants; Contamination; Decontamination. Miscellaneous; Diesel; diesel fuel; Diesel fuels; Environmental Pollution - analysis; Environmental Restoration and Remediation - methods; Exact sciences and technology; Feasibility Studies; Fuel oil; fuel oils; Fuel Oils - analysis; Fuels; Hydrocarbons - analysis; hydrogen; Hydrogen peroxide; Hydrogen Peroxide - chemistry; Kinetics; Manganese Compounds - chemistry; Oxidants; Oxidants - chemistry; Oxidation; Oxides - chemistry; Oxidizing agents; Permanganate; Persulfate oxidation; petroleum; Petroleum - analysis; polluted soils; Pollution; Reactors; Sodium Compounds - chemistry; Soil (material); Soil and sediments pollution; Soil Pollutants - analysis; soil remediation; Sulfates - chemistry
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2010.12.129

In this study, batch experiments were conducted to evaluate the feasibility of petroleum-hydrocarbon contaminated soil remediation using persulfate oxidation. Various controlling factors including different persulfate and ferrous ion concentrations, different oxidants (persulfate, hydrogen peroxide, and permanganate), and different contaminants (diesel and fuel oil) were considered. Results show that persulfate oxidation is capable of treating diesel and fuel oil contaminated soil. Higher persulfate and ferrous ion concentrations resulted in higher diesel degrading rates within the applied persulfate/ferrous ion molar ratios. A two-stage diesel degradation was observed in the batch experiments. In addition, treatment of diesel-contaminated soil using in situ metal mineral activation under ambient temperature (e.g., 25°C) may be a feasible option for site remediation. Results also reveal that persulfate anions could persist in the system for more than five months. Thus, sequential injections of ferrous ion to generate sulfate free radicals might be a feasible way to enhance contaminant oxidation. Diesel oxidation efficiency and rates by the three oxidants followed the sequence of hydrogen peroxide>permanganate>persulfate in the limited timeframes. Results of this study indicate that the application of persulfate oxidation is a feasible method to treat soil contaminated by diesel and fuel oil.