Calix[2]-m-benzo[4]phyrin with Aggregation-Induced Enhanced-Emission Characteristics: Application as a HgII Chemosensor

Quenched by mercury: A hybrid, core‐modified, expanded calixphyrin was synthesized, confirmed by single‐crystal X‐ray analysis, and found to exhibit aggregation‐induced enhanced‐emission (AIEE) characteristics. The aggregate formation was confirmed by HR‐TEM analysis. The efficient emission in aqueo...

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Published in:Chemistry : a European journal 2011-06, Vol.17 (24), p.6598-6601
Main Authors: Salini, P. S., Thomas, Ajesh P., Sabarinathan, R., Ramakrishnan, S., Sreedevi, K. C. Gowri, Reddy, M. L. P., Srinivasan, A.
Format: Article
Language:English
Subjects:
Calixarenes - chemistry
calixphyrins
Chemistry
chemosensors
Crystallography, X-Ray
fluoresence
Hydrogen Bonding
hydrogen bonds
macrocycles
Macrocyclic Compounds - chemistry
Mercury - chemistry
Molecular Structure
Porphyrins - chemistry
Spectrometry, Fluorescence
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container_end_page 6601
container_issue 24
container_start_page 6598
container_title Chemistry : a European journal
container_volume 17
creator Salini, P. S.
Thomas, Ajesh P.
Sabarinathan, R.
Ramakrishnan, S.
Sreedevi, K. C. Gowri
Reddy, M. L. P.
Srinivasan, A.
description Quenched by mercury: A hybrid, core‐modified, expanded calixphyrin was synthesized, confirmed by single‐crystal X‐ray analysis, and found to exhibit aggregation‐induced enhanced‐emission (AIEE) characteristics. The aggregate formation was confirmed by HR‐TEM analysis. The efficient emission in aqueous solution and in the solid state was utilized for metal‐ion‐sensing studies, which concluded a potential application for selective detection of HgII ions (see graphic).
doi_str_mv 10.1002/chem.201100046
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subjects Calixarenes - chemistry
calixphyrins
Chemistry
chemosensors
Crystallography, X-Ray
fluoresence
Hydrogen Bonding
hydrogen bonds
macrocycles
Macrocyclic Compounds - chemistry
Mercury - chemistry
Molecular Structure
Porphyrins - chemistry
Spectrometry, Fluorescence
title Calix[2]-m-benzo[4]phyrin with Aggregation-Induced Enhanced-Emission Characteristics: Application as a HgII Chemosensor
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