Effect of boron addition on the structure and properties of iron phosphate glasses

• Published in: Journal of non-crystalline solids 2011-03, Vol.357 (5), p.1455-1462
• Main Authors: Karabulut, M., Yuce, B., Bozdogan, O., Ertap, H., Mammadov, G.M.
• Format: Article
• Language: English
• Subjects: Boron; Chemical durability; Condensed matter: structure, mechanical and thermal properties; Crystallization; Disordered solids; Exact sciences and technology; Glass; Glasses; Infrared radiation; Iron; Iron borophosphate glasses; Mössbauer; Phosphate glass; Physics; Radioactive waste; Spectra; Spectroscopy; Structure of solids and liquids; crystallography; Thermal stability; Vitrification
• ISSN: 0022-3093; 1873-4812
• DOI: 10.1016/j.jnoncrysol.2010.11.023

Effects of boron addition on the glass forming characteristics, structure and properties of iron phosphate glasses with nominal compositions of xB 2O 3–(40−x)Fe 2O 3–60P 2O 5 (x = 2–20, mol%) and xB 2O 3–(100−x)[Fe 2O 3–60P 2O 5] (x = 2–20, mol%) have been investigated by DTA, XRD, IR and Mössbauer spectroscopy. Although there were some weak local surface crystallizations on especially most of the glasses in group B, all of the compositions formed glass. DTA spectra showed two exothermic peaks corresponding to crystallizations along with an endothermic glass transition peak. T g increased with increasing B 2O 3 content for the glasses in the first series which indicates that the addition of B 2O 3 increases the thermal stability of glasses in this series while the opposite is observed in the second series. The dissolution rates of boron containing bulk glasses were found to be around 10 −9 gr/cm 2 min which are comparable to that of the base iron phosphate glass. When the B 2O 3 content was above 14%, new bands related to BO 4 tetrahedral groups have been observed in the IR spectra. The Mössbauer isomer shift values of boron doped glasses were found to be a little lower than that of base glass but both iron ions had distorted octahedral coordination in all glasses. The fraction of Fe 2+ ions in glasses (Fe 2+/∑(Fe 2+ + Fe 3+)) was found to be 23% for the base glass while it was 10–22% for the boron doped glasses. ► Boron containing iron phosphate glasses were prepared in two series. ► Addition of B 2O 3 for Fe 2O 3 in the glass composition increases thermal stability of glass. ► Chemical durability of boron containing glasses is comparable to the base glass. ► Structure of glasses has been investigated by XRD, IR, and Mössbauer spectroscopy.