Mechanical behaviour of a poydimethylsiloxane elastomer after outdoor weathering in two different weathering locations

• Published in: Polymer degradation and stability 2011-04, Vol.96 (4), p.470-476
• Main Authors: Eleni, Panagiota N., Krokida, Magdalini K., Polyzois, Gregory L., Charitidis, Constantinos A., Koumoulos, Elias P., Tsikourkitoudi, Vasiliki P., Ziomas, Ioannis
• Format: Article
• Language: English
• Subjects: Ageing; Analysis of variance; Applied sciences; Biological and medical sciences; Compression; Compression tests; Degradation; Elastomers; Exact sciences and technology; hydrolysis; irradiation; Medical sciences; Nanoindentation; Nanoindentation analysis; Natural weathering; Outdoor; photolysis; Physical properties; Polydimethylsiloxane; Polymer industry, paints, wood; Properties and testing; prostheses; Prosthetics; solar radiation; Surgery (general aspects). Transplantations, organ and tissue grafts. Graft diseases; Surgical implants; Technology of polymers; Technology. Biomaterials. Equipments; Tensile testing; Weathering
• ISSN: 0141-3910; 1873-2321
• DOI: 10.1016/j.polymdegradstab.2011.01.017

The degradation of maxillofacial prosthetic elastomers that occur during physical weathering is usually responsible for the replacement of the prosthesis. In this study the mechanical behaviour of a polydimethylsiloxane (PDMS) elastomer was investigated, after 1 year outdoor weathering in two different weathering locations in Greece (Thessaloniki, Athens). The hypothesis investigated was that irradiation time did not affect the measured properties. Specimens (Elastomer 42) were prepared according to manufacturer’s instructions and exposed to solar radiation for 1 year. Compression, tensile and nanoindentation tests were performed before and after the exposure. Compression and tensile data were also subjected to analysis of variance (ANOVA) and Tukey Post hoc tests at a level of α = .05. These properties were selected due to their clinical significance for fabrication and maintenance of a facial prosthesis. According to statistical analysis all the measured properties changed significantly after outdoor weathering. More specifically, most of the properties presented significant changes after six months of weathering. The observed changes also depended on the weathering locations. The hypothesis investigated was rejected. Material A became harder and the observed differences in the mechanical behaviour resulted from photo-degradation and hydrolysis that might occur due to weathering. The study also provides new information about maxillofacial prosthetics serviceability obtained from nanoindentation tests.