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Effect of deashing rice straws on their derived activated carbons produced by phosphoric acid activation
We studied the effect of physically and/or chemically deashing rice straw (RS) on the adsorption capacity of their derived activated carbons (ACs) produced by chemical activation with H 3PO 4. Surface area and pore volumes were determined by nitrogen adsorption at 77 K. Methylene blue adsorption iso...
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Published in: | Biomass & bioenergy 2011-05, Vol.35 (5), p.1954-1959 |
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container_end_page | 1959 |
container_issue | 5 |
container_start_page | 1954 |
container_title | Biomass & bioenergy |
container_volume | 35 |
creator | Basta, A.H. Fierro, V. Saied, H. Celzard, A. |
description | We studied the effect of physically and/or chemically deashing rice straw (RS) on the adsorption capacity of their derived activated carbons (ACs) produced by chemical activation with H
3PO
4. Surface area and pore volumes were determined by nitrogen adsorption at 77 K. Methylene blue adsorption isotherms onto ACs were carried out, and we applied Langmuir and Freundlich models to fit the adsorption data. We showed that preliminary deashing does not bring significant improvement to the resultant ACs’ properties. ACs prepared by H
3PO
4 activation of raw and deashed RS have intermediate performances between those of ACs prepared by 1- and 2-step KOH activation, but are much cheaper to produce.
► In Egypt, RS is mainly considered as a waste and most of the times RS is burnt without any profit and caused atmospheric pollution. ► This article presents an overview of research studies carried out on biomass valorization. ► The production of activated carbon from deashed RS and phosphoric acid was evaluated. |
doi_str_mv | 10.1016/j.biombioe.2011.01.043 |
format | article |
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3PO
4. Surface area and pore volumes were determined by nitrogen adsorption at 77 K. Methylene blue adsorption isotherms onto ACs were carried out, and we applied Langmuir and Freundlich models to fit the adsorption data. We showed that preliminary deashing does not bring significant improvement to the resultant ACs’ properties. ACs prepared by H
3PO
4 activation of raw and deashed RS have intermediate performances between those of ACs prepared by 1- and 2-step KOH activation, but are much cheaper to produce.
► In Egypt, RS is mainly considered as a waste and most of the times RS is burnt without any profit and caused atmospheric pollution. ► This article presents an overview of research studies carried out on biomass valorization. ► The production of activated carbon from deashed RS and phosphoric acid was evaluated.</description><identifier>ISSN: 0961-9534</identifier><identifier>EISSN: 1873-2909</identifier><identifier>DOI: 10.1016/j.biombioe.2011.01.043</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Activated carbon ; Adsorption ; Applied sciences ; Chemical activation ; Energy ; Exact sciences and technology ; Fuel processing. Carbochemistry and petrochemistry ; Fuels ; methylene blue ; Oryza sativa ; Phosphoric acid ; rice ; Rice straw ; Solid fuel processing (coal, coke, brown coal, peat, wood, etc.) ; sorption isotherms ; surface area</subject><ispartof>Biomass & bioenergy, 2011-05, Vol.35 (5), p.1954-1959</ispartof><rights>2011 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c398t-4f0a91328d95df8a772e477c76a8403890af0ecf880d25b4de789eb873e23cd83</citedby><cites>FETCH-LOGICAL-c398t-4f0a91328d95df8a772e477c76a8403890af0ecf880d25b4de789eb873e23cd83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24115326$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Basta, A.H.</creatorcontrib><creatorcontrib>Fierro, V.</creatorcontrib><creatorcontrib>Saied, H.</creatorcontrib><creatorcontrib>Celzard, A.</creatorcontrib><title>Effect of deashing rice straws on their derived activated carbons produced by phosphoric acid activation</title><title>Biomass & bioenergy</title><description>We studied the effect of physically and/or chemically deashing rice straw (RS) on the adsorption capacity of their derived activated carbons (ACs) produced by chemical activation with H
3PO
4. Surface area and pore volumes were determined by nitrogen adsorption at 77 K. Methylene blue adsorption isotherms onto ACs were carried out, and we applied Langmuir and Freundlich models to fit the adsorption data. We showed that preliminary deashing does not bring significant improvement to the resultant ACs’ properties. ACs prepared by H
3PO
4 activation of raw and deashed RS have intermediate performances between those of ACs prepared by 1- and 2-step KOH activation, but are much cheaper to produce.
► In Egypt, RS is mainly considered as a waste and most of the times RS is burnt without any profit and caused atmospheric pollution. ► This article presents an overview of research studies carried out on biomass valorization. ► The production of activated carbon from deashed RS and phosphoric acid was evaluated.</description><subject>Activated carbon</subject><subject>Adsorption</subject><subject>Applied sciences</subject><subject>Chemical activation</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>Fuel processing. Carbochemistry and petrochemistry</subject><subject>Fuels</subject><subject>methylene blue</subject><subject>Oryza sativa</subject><subject>Phosphoric acid</subject><subject>rice</subject><subject>Rice straw</subject><subject>Solid fuel processing (coal, coke, brown coal, peat, wood, etc.)</subject><subject>sorption isotherms</subject><subject>surface area</subject><issn>0961-9534</issn><issn>1873-2909</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkU1vEzEQQC0EEqHwF8AXxGnD-CO79g1UFVqpEgfo2Zq1x42jZB3sTar-exxSekXyyJb9Zjx-Zuy9gKUA0X_eLMeUdy1oKUGIJbSh1Qu2EGZQnbRgX7IF2F50dqX0a_am1g2A0KDFgq2vYiQ_8xx5IKzrNN3zkjzxOhd8qDxPfF5TKu20pCMFjn5OR5zbymMZ81T5vuRw8G1jfOT7da4tWoUGpmc65ektexVxW-nd03zB7r5d_bq87m5_fL-5_HrbeWXN3OkIaIWSJthViAaHQZIeBj_0aDQoYwEjkI_GQJCrUQcajKWxvZSk8sGoC_bpXLe19ftAdXa7VD1ttzhRPlRnBimU0fJE9mfSl1xroej2Je2wPDoB7mTWbdw_s-5k1kEbWrXEj09XYPW4jQUnn-pzttRCrJTsG_fhzEXMDu9LY-5-ypN5AKXhL_HlTFAzckxUXPWJpiYzlfYrLuT0v2b-AHqZnKE</recordid><startdate>20110501</startdate><enddate>20110501</enddate><creator>Basta, A.H.</creator><creator>Fierro, V.</creator><creator>Saied, H.</creator><creator>Celzard, A.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>FBQ</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>7ST</scope><scope>7U6</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>P64</scope><scope>SOI</scope></search><sort><creationdate>20110501</creationdate><title>Effect of deashing rice straws on their derived activated carbons produced by phosphoric acid activation</title><author>Basta, A.H. ; Fierro, V. ; Saied, H. ; Celzard, A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c398t-4f0a91328d95df8a772e477c76a8403890af0ecf880d25b4de789eb873e23cd83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Activated carbon</topic><topic>Adsorption</topic><topic>Applied sciences</topic><topic>Chemical activation</topic><topic>Energy</topic><topic>Exact sciences and technology</topic><topic>Fuel processing. Carbochemistry and petrochemistry</topic><topic>Fuels</topic><topic>methylene blue</topic><topic>Oryza sativa</topic><topic>Phosphoric acid</topic><topic>rice</topic><topic>Rice straw</topic><topic>Solid fuel processing (coal, coke, brown coal, peat, wood, etc.)</topic><topic>sorption isotherms</topic><topic>surface area</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Basta, A.H.</creatorcontrib><creatorcontrib>Fierro, V.</creatorcontrib><creatorcontrib>Saied, H.</creatorcontrib><creatorcontrib>Celzard, A.</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Environment Abstracts</collection><collection>Sustainability Science Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environment Abstracts</collection><jtitle>Biomass & bioenergy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Basta, A.H.</au><au>Fierro, V.</au><au>Saied, H.</au><au>Celzard, A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of deashing rice straws on their derived activated carbons produced by phosphoric acid activation</atitle><jtitle>Biomass & bioenergy</jtitle><date>2011-05-01</date><risdate>2011</risdate><volume>35</volume><issue>5</issue><spage>1954</spage><epage>1959</epage><pages>1954-1959</pages><issn>0961-9534</issn><eissn>1873-2909</eissn><abstract>We studied the effect of physically and/or chemically deashing rice straw (RS) on the adsorption capacity of their derived activated carbons (ACs) produced by chemical activation with H
3PO
4. Surface area and pore volumes were determined by nitrogen adsorption at 77 K. Methylene blue adsorption isotherms onto ACs were carried out, and we applied Langmuir and Freundlich models to fit the adsorption data. We showed that preliminary deashing does not bring significant improvement to the resultant ACs’ properties. ACs prepared by H
3PO
4 activation of raw and deashed RS have intermediate performances between those of ACs prepared by 1- and 2-step KOH activation, but are much cheaper to produce.
► In Egypt, RS is mainly considered as a waste and most of the times RS is burnt without any profit and caused atmospheric pollution. ► This article presents an overview of research studies carried out on biomass valorization. ► The production of activated carbon from deashed RS and phosphoric acid was evaluated.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.biombioe.2011.01.043</doi><tpages>6</tpages></addata></record> |
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subjects | Activated carbon Adsorption Applied sciences Chemical activation Energy Exact sciences and technology Fuel processing. Carbochemistry and petrochemistry Fuels methylene blue Oryza sativa Phosphoric acid rice Rice straw Solid fuel processing (coal, coke, brown coal, peat, wood, etc.) sorption isotherms surface area |
title | Effect of deashing rice straws on their derived activated carbons produced by phosphoric acid activation |
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