Synthesis and structural characterization of the anionic chelates of hypercoordinate silicon, the derivatives of glycolic and tartaric acids

Reactions of 1-(trimethoxysilylmethyl)-2-piperidone with glycolic and ( R, R)-tartaric acids in the presence of dicyclohexylamine afford cation–anionic complexes with different coordination states of the Si atoms.

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Bibliographic Details
Published in:Mendeleev communications 2010-09, Vol.20 (5), p.273-274
Main Authors: Shipov, Aleksandr G., Korlyukov, Alexander A., Arkhipov, Dmitry E., Kramarova, Evgeniya P., Negrebetskii, Vadim V., Bylikin, Sergey Yu, Nikolin, Alexey A., Fan, Huntse, Antipin, Mikhail Yu, Baukov, Yuri I.
Format: Article
Language:English
Subjects:
Cations
Chelates
Derivatives
Silicon
Synthesis
Tartaric acid
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Summary:Reactions of 1-(trimethoxysilylmethyl)-2-piperidone with glycolic and ( R, R)-tartaric acids in the presence of dicyclohexylamine afford cation–anionic complexes with different coordination states of the Si atoms.
ISSN:0959-9436
DOI:10.1016/j.mencom.2010.09.011