Mimicking Natural Fibrous Structures of Opals by Means of a Microemulsion-Mediated Hydrothermal Method

Silica-based nanomaterials are of great interest because of their potential applications in constructing electronic and optoelectronic nanodevices. Especially significant are those that combine the properties of photonic crystal with a fibrous semiconductor structure. Here we report the use of micro...

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Bibliographic Details
Published in:Langmuir 2011-07, Vol.27 (14), p.8905-8912
Main Authors: Hassan, Natalia, Verdinelli, Valeria, Ruso, Juan M, Messina, Paula V
Format: Article
Language:English
Subjects:
Chemistry
Colloidal state and disperse state
Emulsions. Microemulsions. Foams
Exact sciences and technology
General and physical chemistry
Materials: Nano-and Mesostructured Materials, Polymers, Gels, Liquid Crystals, Composites
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Summary:Silica-based nanomaterials are of great interest because of their potential applications in constructing electronic and optoelectronic nanodevices. Especially significant are those that combine the properties of photonic crystal with a fibrous semiconductor structure. Here we report the use of microemulsion droplet systems as a simple and controllable route for the synthesis of 3D opals materials with an unusual fibrous microstructure similar to those that exist in nature. By this method, we demonstrate the creation of very long fibrils of 30–50 nm diameter and more than 20 μm length showing simultaneous short and long wavelength light emissions and band gap values (5.50 and 4.41 eV) comparable to those obtained for silicon-based metal oxide semiconductors.
ISSN:0743-7463
1520-5827
DOI:10.1021/la201555f