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Magnetic properties and large magnetocaloric effect in Gd–Ni amorphous ribbons for magnetic refrigeration applications in intermediate temperature range
► We report that the first crystallization temperature T x1 of Gd 68− x Ni 32+ x amorphous ribbons with x = −3, 0, and 3 were 561, 568, and 562 K, respectively. ► All the samples underwent the second-order magnetic transitions at temperatures between ∼122 ( x = −3 and 3) and 124 K ( x = 0). ► The ma...
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Published in: | Journal of alloys and compounds 2011-06, Vol.509 (24), p.6889-6892 |
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Main Authors: | , , , , , , , |
Format: | Article |
Language: | English |
Subjects: | |
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Online Access: | Get full text |
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Summary: | ► We report that the first crystallization temperature
T
x1
of Gd
68−
x
Ni
32+
x
amorphous ribbons with
x
=
−3, 0, and 3 were 561, 568, and 562
K, respectively. ► All the samples underwent the second-order magnetic transitions at temperatures between ∼122 (
x
=
−3 and 3) and 124
K (
x
=
0). ► The maximum isothermal magnetic entropy changes (−Δ
S
M)
max of Gd
71Ni
29, Gd
68Ni
32, and Gd
65Ni
35 amorphous ribbons with a magnetic field change of 0–5
T were 9.0, 8.0, and 6.9
J
kg
−1
k
−1, respectively. ► Large refrigerant capacity (RC) values were also obtained in these ribbons. For example, Gd
71Ni
29 amorphous ribbon has a maximum RC value of 724
J
kg
−1. ► Large magnetic entropy change and RC values, as well as high stability enable Gd
71Ni
29 amorphous ribbon to be a competitive candidate among the magnetic refrigeration materials working at temperatures near 120
K.
Amorphous Gd
68−
x
Ni
32+
x
(
x
=
−3, 0, 3) ribbons were prepared by melt-spinning method. The crystallization onset temperatures
T
x1
for Gd
68−
x
Ni
32+
x
amorphous ribbons with
x
=
−3, 0, and 3 are 561, 568, and 562
K, respectively. All the samples undergo the second-order magnetic transition at temperatures between ∼122 (
x
=
−3 and 3) and 124
K (
x
=
0). The Curie temperature
T
C does not change with the composition significantly. The maximum isothermal magnetic entropy changes (−Δ
S
M)
max of Gd
71Ni
29, Gd
68Ni
32, and Gd
65Ni
35 amorphous ribbons for a magnetic field change of 0–5
T were 9.0, 8.0, and 6.9
J
kg
−1
K
−1, respectively. Large values of the refrigerant capacity (RC) were obtained in these ribbons. For example, Gd
71Ni
29 amorphous ribbon has a maximum RC value of 724
J
kg
−1. Large magnetic entropy change and RC values together with high stability enable the Gd
71Ni
29 amorphous alloy a competitive candidate among the magnetic refrigeration materials working at temperatures near 120
K. |
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ISSN: | 0925-8388 1873-4669 |
DOI: | 10.1016/j.jallcom.2011.03.173 |