Radical C-glycosylation reaction of pyranosides with the 2,3-trans carbamate group

Radical-mediated C-glycosylation of pyranosides with the 2,3-trans carbamate group was investigated. C-Glycosylation was achieved with high α-selectivity.

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2011-09, Vol.47 (34), p.9720-9722
Main Authors: Manabe, Shino, Aihara, Yoshiyuki, Ito, Yukishige
Format: Article
Language:English
Subjects:
Carbamates - chemistry
Glycosides - chemistry
Glycosylation
Pyrans - chemistry
Radicals
Stereoisomerism
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Description
Summary:Radical-mediated C-glycosylation of pyranosides with the 2,3-trans carbamate group was investigated. C-Glycosylation was achieved with high α-selectivity.
ISSN:1359-7345
1364-548X
DOI:10.1039/c1cc13172a