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Surface modification of a commercial thin film composite polyamide reverse osmosis membrane by carbodiimide-induced grafting with poly(ethylene glycol) derivatives
Based on the existing carboxylic acid groups on surface of used commercial thin film composite polyamide reverse osmosis membrane, two kinds of poly(ethylene glycol) derivatives with different chains were grafted by carbodiimide-induced method to improve the antifouling property. The membranes befor...
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Published in: | Desalination 2011-07, Vol.275 (1-3), p.252-259 |
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container_title | Desalination |
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creator | Kang, Guodong Yu, Haijun Liu, Zhongnan Cao, Yiming |
description | Based on the existing carboxylic acid groups on surface of used commercial thin film composite polyamide reverse osmosis membrane, two kinds of poly(ethylene glycol) derivatives with different chains were grafted by carbodiimide-induced method to improve the antifouling property. The membranes before and after modification were characterized by attenuated total reflectance Fourier transform infrared spectroscopy, scanning electron microscopy, atomic force microscopy, X-ray photoelectron spectroscopy and static contact angle measurement. Moreover, the water flux, NaCl rejection and fouling experiments were also conducted. The changes of chemical composition and morphology on membrane surfaces indicated the successful grafting of poly(ethylene glycol) derivatives. Compared to unmodified membrane, the modified membranes were more resistant to fouling in protein and cationic surfactant feeding solutions. The method in this study provided a new way for surface modification of commercial polyamide reverse osmosis membranes. |
doi_str_mv | 10.1016/j.desal.2011.03.007 |
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The membranes before and after modification were characterized by attenuated total reflectance Fourier transform infrared spectroscopy, scanning electron microscopy, atomic force microscopy, X-ray photoelectron spectroscopy and static contact angle measurement. Moreover, the water flux, NaCl rejection and fouling experiments were also conducted. The changes of chemical composition and morphology on membrane surfaces indicated the successful grafting of poly(ethylene glycol) derivatives. Compared to unmodified membrane, the modified membranes were more resistant to fouling in protein and cationic surfactant feeding solutions. The method in this study provided a new way for surface modification of commercial polyamide reverse osmosis membranes.</description><subject>Applied sciences</subject><subject>atomic force microscopy</subject><subject>chemical composition</subject><subject>Chemical engineering</subject><subject>contact angle</subject><subject>Derivatives</subject><subject>desalination</subject><subject>ethylene glycol</subject><subject>Exact sciences and technology</subject><subject>Fouling</subject><subject>Fourier transform infrared spectroscopy</subject><subject>Glycols</subject><subject>Grafting</subject><subject>Membrane separation (reverse osmosis, dialysis...)</subject><subject>Membranes</subject><subject>Pollution</subject><subject>Polyamide resins</subject><subject>reflectance</subject><subject>Reverse osmosis</subject><subject>scanning electron microscopy</subject><subject>surfactants</subject><subject>Thin films</subject><subject>X-ray photoelectron spectroscopy</subject><issn>0011-9164</issn><issn>1873-4464</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNo9kc1uGyEUhVHVSnXdPEEXZVO1XcyEvxkzyyrqnxSpiyRrxMDFxoLBhbGjeZ6-aHAclc0V3HM-ce9B6AMlLSW0v963FooOLSOUtoS3hGxeoRWVG94I0YvXaEVqpxloL96id6Xs65UNnK_Qv7tjdtoAjsl6542efZpwclhjk2KEbLwOeN75CTsf4vnxkIqfAR9SWHT0FnCGE-QCOJVYWwVHiGPWE-BxwUbnsZL9Wdj4yR4NWLzN2s1-2uJHP--eQV9g3i0BqmcbFpPCV2wh-1P9zQnKe_TG6VDg6qWu0cOP7_c3v5rbPz9_33y7bQzn3dy4wXVgddcPlpC-jlqPk9qNlrnBMMLNSKXeSAaMcmb7TsiuA9FL6xgVzvA1-nzhHnL6e4Qyq-iLgRDqLOlYlJSSko0YWFXyi9LkVEoGpw7ZR50XRYk6J6L26jkRdU5EEa5qItX16YWvi9HB1R0ZX_5bmWCS0ZrKGn286JxOSm9z1TzcVVBHCBkqT_InLoObQQ</recordid><startdate>20110715</startdate><enddate>20110715</enddate><creator>Kang, Guodong</creator><creator>Yu, Haijun</creator><creator>Liu, Zhongnan</creator><creator>Cao, Yiming</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>FBQ</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>FR3</scope><scope>KR7</scope></search><sort><creationdate>20110715</creationdate><title>Surface modification of a commercial thin film composite polyamide reverse osmosis membrane by carbodiimide-induced grafting with poly(ethylene glycol) derivatives</title><author>Kang, Guodong ; Yu, Haijun ; Liu, Zhongnan ; Cao, Yiming</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c335t-f9f5eda569d006164444f8afbd2f9c203cb18a782e2132d654855e468df214fc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Applied sciences</topic><topic>atomic force microscopy</topic><topic>chemical composition</topic><topic>Chemical engineering</topic><topic>contact angle</topic><topic>Derivatives</topic><topic>desalination</topic><topic>ethylene glycol</topic><topic>Exact sciences and technology</topic><topic>Fouling</topic><topic>Fourier transform infrared spectroscopy</topic><topic>Glycols</topic><topic>Grafting</topic><topic>Membrane separation (reverse osmosis, dialysis...)</topic><topic>Membranes</topic><topic>Pollution</topic><topic>Polyamide resins</topic><topic>reflectance</topic><topic>Reverse osmosis</topic><topic>scanning electron microscopy</topic><topic>surfactants</topic><topic>Thin films</topic><topic>X-ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kang, Guodong</creatorcontrib><creatorcontrib>Yu, Haijun</creatorcontrib><creatorcontrib>Liu, Zhongnan</creatorcontrib><creatorcontrib>Cao, Yiming</creatorcontrib><collection>AGRIS</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><jtitle>Desalination</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kang, Guodong</au><au>Yu, Haijun</au><au>Liu, Zhongnan</au><au>Cao, Yiming</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Surface modification of a commercial thin film composite polyamide reverse osmosis membrane by carbodiimide-induced grafting with poly(ethylene glycol) derivatives</atitle><jtitle>Desalination</jtitle><date>2011-07-15</date><risdate>2011</risdate><volume>275</volume><issue>1-3</issue><spage>252</spage><epage>259</epage><pages>252-259</pages><issn>0011-9164</issn><eissn>1873-4464</eissn><coden>DSLNAH</coden><abstract>Based on the existing carboxylic acid groups on surface of used commercial thin film composite polyamide reverse osmosis membrane, two kinds of poly(ethylene glycol) derivatives with different chains were grafted by carbodiimide-induced method to improve the antifouling property. 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subjects | Applied sciences atomic force microscopy chemical composition Chemical engineering contact angle Derivatives desalination ethylene glycol Exact sciences and technology Fouling Fourier transform infrared spectroscopy Glycols Grafting Membrane separation (reverse osmosis, dialysis...) Membranes Pollution Polyamide resins reflectance Reverse osmosis scanning electron microscopy surfactants Thin films X-ray photoelectron spectroscopy |
title | Surface modification of a commercial thin film composite polyamide reverse osmosis membrane by carbodiimide-induced grafting with poly(ethylene glycol) derivatives |
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