The nature and photochemistry of 2,2-dimethyloxirane radical cations in freonic matrices at 77 K

The X-ray irradiation of 2,2-dimethyloxirane in freonic matrices at 77 K results in the trapping of a cyclic radical cation form, presumably, complexed with a matrix molecule, which transforms into a C-centered distonic radical cation under the action of light.

Saved in:
Bibliographic Details
Published in:Mendeleev communications 2011-05, Vol.21 (3), p.155-156
Main Authors: Sorokin, Ivan D., Feldman, Vladimir I., Mel’nikova, Ol’ga L., Pergushov, Vladimir I., Tyurin, Daniil A., Mel’nikov, Mikhail Ya
Format: Article
Language:English
Subjects:
Cations
Mathematical analysis
Matrices
Matrix methods
Radicals
Transforms
Trapping
X-rays
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The X-ray irradiation of 2,2-dimethyloxirane in freonic matrices at 77 K results in the trapping of a cyclic radical cation form, presumably, complexed with a matrix molecule, which transforms into a C-centered distonic radical cation under the action of light.
ISSN:0959-9436
DOI:10.1016/j.mencom.2011.04.015