Development of a novel hydrophobic/hydrophilic double micro porous layer for use in a cathode gas diffusion layer in PEMFC

• Published in: International journal of hydrogen energy 2011-07, Vol.36 (14), p.8422-8428
• Main Authors: Chun, Jeong Hwan, Park, Ki Tae, Jo, Dong Hyun, Lee, Ji Young, Kim, Sang Gon, Park, Sun Hee, Lee, Eun Sook, Jyoung, Jy-Young, Kim, Sung Hyun
• Format: Article
• Language: English
• Subjects: Alternative fuels. Production and utilization; Applied sciences; Backing; Energy; Exact sciences and technology; Fuel cells; Fuels; Gas diffusion; Gas diffusion layer (GDL); Humidification; Humidity; Hydrogen; Hydrophobic/hydrophilic double layer; Micro porous layer (MPL); Permeability; Polymer electrolyte membrane fuel cell (PEMFC); Water absorption; Water management
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2011.04.038

In this study, a gas diffusion layer (GDL) was modified to improve the water management ability of a proton exchange membrane fuel cell (PEMFC). We developed a novel hydrophobic/hydrophilic double micro porous layer (MPL) that was coated on a gas diffusion backing layer (GDBL). The water management properties, vapor and water permeability, of the GDL were measured and the performance of single cells was evaluated under two different humidification conditions, R.H. 100% and 50%. The modified GDL, which contained a hydrophilic MPL in the middle of the GDL and a hydrophobic MPL on the surface, performed better than the conventional GDL, which contained only a single hydrophobic MPL, regardless of humidity, where the performance of the single cell was significantly improved under the low humidification condition. The hydrophilic MPL, which was in the middle of the modified GDL, was shown to act as an internal humidifier due to its water absorption ability as assessed by measuring the vapor and water permeability of this layer. ► We developed a novel hydrophobic/hydrophilic double micro porous layer. ► The water management properties of the MPL were characterized. ► The MPL had water absorption ability due to its hydrophilic layer. ► The MPL acted as an internal humidifier during single cell operation. ► The single cell performance was fairly improved under low humidification condition.