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Complexes of some 3d metal ions of the Schiff's base, N, N′-di-4-(4′-pentyloxybenzoate) salicylidene-1″, 3″-diamino-2″-propanol: Synthesis and spectral studies
A nematogenic Schiff's base, N,N′-di-4-(4′-pentyloxybenzoate)salicylidene-l″, 3″-diamino-2″-propanol, (abbreviated as H 2L 6), was synthesized and its structure studied by elemental analyses, mass, NMR and IR spectra. The Schiff's base behaves as a dinegative hexa/tetradentate species in i...
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| Published in: | Materials Science & Engineering C 2011-07, Vol.31 (5), p.1111-1114 |
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| Main Authors: | , , , |
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| cited_by | cdi_FETCH-LOGICAL-c376t-e1d1d41fd64e90557976420e42f315ec0d018c77d0e76d93343613a2907036573 |
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| cites | cdi_FETCH-LOGICAL-c376t-e1d1d41fd64e90557976420e42f315ec0d018c77d0e76d93343613a2907036573 |
| container_end_page | 1114 |
| container_issue | 5 |
| container_start_page | 1111 |
| container_title | Materials Science & Engineering C |
| container_volume | 31 |
| creator | Kumar Singh, Angad Kumari, Sanyucta Shakya, Pawan Raj Rao, T.R. |
| description | A nematogenic Schiff's base,
N,N′-di-4-(4′-pentyloxybenzoate)salicylidene-l″, 3″-diamino-2″-propanol, (abbreviated as H
2L
6), was synthesized and its structure studied by elemental analyses, mass, NMR and IR spectra. The Schiff's base behaves as a dinegative hexa/tetradentate species in its metal complexes of the general formula, [ML
6]
n where M
II═Mn, Co, Ni, Cu and Zn. Their structural characterizations were made by various spectroscopic techniques.
► The work reveals the synthesis and spectral Studies of some 3d metal complexes. ► The mesogenic ligand yielded the metallomesogenic Cu
II complex. ► We have included the non-mesogenic Mn
II, Co
II, Ni
II and Zn
II complexes. ► The spectral studies for investigating the bonding nature of the ligand. ► Besides the physical characteristics and geometry of the complexes. |
| doi_str_mv | 10.1016/j.msec.2011.04.006 |
| format | article |
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N,N′-di-4-(4′-pentyloxybenzoate)salicylidene-l″, 3″-diamino-2″-propanol, (abbreviated as H
2L
6), was synthesized and its structure studied by elemental analyses, mass, NMR and IR spectra. The Schiff's base behaves as a dinegative hexa/tetradentate species in its metal complexes of the general formula, [ML
6]
n where M
II═Mn, Co, Ni, Cu and Zn. Their structural characterizations were made by various spectroscopic techniques.
► The work reveals the synthesis and spectral Studies of some 3d metal complexes. ► The mesogenic ligand yielded the metallomesogenic Cu
II complex. ► We have included the non-mesogenic Mn
II, Co
II, Ni
II and Zn
II complexes. ► The spectral studies for investigating the bonding nature of the ligand. ► Besides the physical characteristics and geometry of the complexes.</description><identifier>ISSN: 0928-4931</identifier><identifier>EISSN: 1873-0191</identifier><identifier>DOI: 10.1016/j.msec.2011.04.006</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Biomimetic materials ; Infrared radiation ; Metallomesogens ; Nematogenic ; Nickel ; NMR and IR spectra ; Schiff bases ; Schiff's base ; Spectra ; Spectroscopy ; Square-pyramidal ; Synthesis ; Zinc</subject><ispartof>Materials Science & Engineering C, 2011-07, Vol.31 (5), p.1111-1114</ispartof><rights>2011 Elsevier B.V.</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c376t-e1d1d41fd64e90557976420e42f315ec0d018c77d0e76d93343613a2907036573</citedby><cites>FETCH-LOGICAL-c376t-e1d1d41fd64e90557976420e42f315ec0d018c77d0e76d93343613a2907036573</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Kumar Singh, Angad</creatorcontrib><creatorcontrib>Kumari, Sanyucta</creatorcontrib><creatorcontrib>Shakya, Pawan Raj</creatorcontrib><creatorcontrib>Rao, T.R.</creatorcontrib><title>Complexes of some 3d metal ions of the Schiff's base, N, N′-di-4-(4′-pentyloxybenzoate) salicylidene-1″, 3″-diamino-2″-propanol: Synthesis and spectral studies</title><title>Materials Science & Engineering C</title><description>A nematogenic Schiff's base,
N,N′-di-4-(4′-pentyloxybenzoate)salicylidene-l″, 3″-diamino-2″-propanol, (abbreviated as H
2L
6), was synthesized and its structure studied by elemental analyses, mass, NMR and IR spectra. The Schiff's base behaves as a dinegative hexa/tetradentate species in its metal complexes of the general formula, [ML
6]
n where M
II═Mn, Co, Ni, Cu and Zn. Their structural characterizations were made by various spectroscopic techniques.
► The work reveals the synthesis and spectral Studies of some 3d metal complexes. ► The mesogenic ligand yielded the metallomesogenic Cu
II complex. ► We have included the non-mesogenic Mn
II, Co
II, Ni
II and Zn
II complexes. ► The spectral studies for investigating the bonding nature of the ligand. ► Besides the physical characteristics and geometry of the complexes.</description><subject>Biomimetic materials</subject><subject>Infrared radiation</subject><subject>Metallomesogens</subject><subject>Nematogenic</subject><subject>Nickel</subject><subject>NMR and IR spectra</subject><subject>Schiff bases</subject><subject>Schiff's base</subject><subject>Spectra</subject><subject>Spectroscopy</subject><subject>Square-pyramidal</subject><subject>Synthesis</subject><subject>Zinc</subject><issn>0928-4931</issn><issn>1873-0191</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNp9Uctu1DAUjRBIDIUfYOVdQaqDXxPHiA0a8ZIqWBTWlmvfqB4ldsjNVA2r_k635Y_6JTgMa6Sr-7DOuQ-fqnrJWc0Zb97s6wHB14JxXjNVM9Y8qja81ZIybvjjasOMaKkykj-tniHuC6CVWmyqu10exh5uAEnuCOYBiAxkgNn1JOb093W-AnLhr2LXnSK5dAhn5Guxh9t7GiJV9JVa0xHSvPT5ZrmE9Cu7GV4TdH30Sx8DJKD84fb3GZHFF5YbYspUrMU45dGl3L8lF0sqozAicSkQHMHPU1kD50OIgM-rJ53rEV78iyfVj48fvu8-0_Nvn77s3p9TL3UzU-CBB8W70CgwbLvVRjdKMFCik3wLngXGW691YKCbYKRUsuHSCcM0k81Wy5Pq9Ni3LPbzADjbIaKHvncJ8gFt2xoljOCmIMUR6aeMOEFnxykOblosZ3aVxe7tKotdZbFM2fLrhfTuSIJyw3WEyaKPkDyEOJWDbcjxf_Q_lReaaQ</recordid><startdate>20110720</startdate><enddate>20110720</enddate><creator>Kumar Singh, Angad</creator><creator>Kumari, Sanyucta</creator><creator>Shakya, Pawan Raj</creator><creator>Rao, T.R.</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>JG9</scope><scope>KR7</scope><scope>L7M</scope></search><sort><creationdate>20110720</creationdate><title>Complexes of some 3d metal ions of the Schiff's base, N, N′-di-4-(4′-pentyloxybenzoate) salicylidene-1″, 3″-diamino-2″-propanol: Synthesis and spectral studies</title><author>Kumar Singh, Angad ; Kumari, Sanyucta ; Shakya, Pawan Raj ; Rao, T.R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c376t-e1d1d41fd64e90557976420e42f315ec0d018c77d0e76d93343613a2907036573</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Biomimetic materials</topic><topic>Infrared radiation</topic><topic>Metallomesogens</topic><topic>Nematogenic</topic><topic>Nickel</topic><topic>NMR and IR spectra</topic><topic>Schiff bases</topic><topic>Schiff's base</topic><topic>Spectra</topic><topic>Spectroscopy</topic><topic>Square-pyramidal</topic><topic>Synthesis</topic><topic>Zinc</topic><toplevel>online_resources</toplevel><creatorcontrib>Kumar Singh, Angad</creatorcontrib><creatorcontrib>Kumari, Sanyucta</creatorcontrib><creatorcontrib>Shakya, Pawan Raj</creatorcontrib><creatorcontrib>Rao, T.R.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Materials Science & Engineering C</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kumar Singh, Angad</au><au>Kumari, Sanyucta</au><au>Shakya, Pawan Raj</au><au>Rao, T.R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Complexes of some 3d metal ions of the Schiff's base, N, N′-di-4-(4′-pentyloxybenzoate) salicylidene-1″, 3″-diamino-2″-propanol: Synthesis and spectral studies</atitle><jtitle>Materials Science & Engineering C</jtitle><date>2011-07-20</date><risdate>2011</risdate><volume>31</volume><issue>5</issue><spage>1111</spage><epage>1114</epage><pages>1111-1114</pages><issn>0928-4931</issn><eissn>1873-0191</eissn><abstract>A nematogenic Schiff's base,
N,N′-di-4-(4′-pentyloxybenzoate)salicylidene-l″, 3″-diamino-2″-propanol, (abbreviated as H
2L
6), was synthesized and its structure studied by elemental analyses, mass, NMR and IR spectra. The Schiff's base behaves as a dinegative hexa/tetradentate species in its metal complexes of the general formula, [ML
6]
n where M
II═Mn, Co, Ni, Cu and Zn. Their structural characterizations were made by various spectroscopic techniques.
► The work reveals the synthesis and spectral Studies of some 3d metal complexes. ► The mesogenic ligand yielded the metallomesogenic Cu
II complex. ► We have included the non-mesogenic Mn
II, Co
II, Ni
II and Zn
II complexes. ► The spectral studies for investigating the bonding nature of the ligand. ► Besides the physical characteristics and geometry of the complexes.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.msec.2011.04.006</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record> |
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| source | ScienceDirect Journals |
| subjects | Biomimetic materials Infrared radiation Metallomesogens Nematogenic Nickel NMR and IR spectra Schiff bases Schiff's base Spectra Spectroscopy Square-pyramidal Synthesis Zinc |
| title | Complexes of some 3d metal ions of the Schiff's base, N, N′-di-4-(4′-pentyloxybenzoate) salicylidene-1″, 3″-diamino-2″-propanol: Synthesis and spectral studies |
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