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Vibrational spectroscopic properties of botallackite-structure basic copper halides
Mid-infrared (4000–400 cm −1) absorption and Raman (4000–95 cm −1) spectra of the series of geometrically frustrated materials, botallackite-structure basic copper halides, α-Cu 2(OH) 3Cl and α-Cu 2(OH) 3Br polycrystalline samples were first, to the best of our knowledge, measured, respectively, to...
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| Published in: | Vibrational spectroscopy 2011-07, Vol.56 (2), p.177-183 |
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| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c341t-8451593ca3607b7c09b3babd1619d6c8ba4ca1f55a1150625f4c3d3a5e7e7b4d3 |
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| cites | cdi_FETCH-LOGICAL-c341t-8451593ca3607b7c09b3babd1619d6c8ba4ca1f55a1150625f4c3d3a5e7e7b4d3 |
| container_end_page | 183 |
| container_issue | 2 |
| container_start_page | 177 |
| container_title | Vibrational spectroscopy |
| container_volume | 56 |
| creator | Liu, Xiao-Dong Hagihala, Masato Zheng, Xu-Guang Guo, Qi-Xin |
| description | Mid-infrared (4000–400
cm
−1) absorption and Raman (4000–95
cm
−1) spectra of the series of geometrically frustrated materials, botallackite-structure basic copper halides, α-Cu
2(OH)
3Cl and α-Cu
2(OH)
3Br polycrystalline samples were first, to the best of our knowledge, measured, respectively, to study the corresponding relationship between their vibrational spectral properties and crystal microstructures. Through the comparative analysis to the four spectra, the authors have definitely assigned or tentatively suggested the vibrational modes of hydroxyl groups in the trimeric hydrogen bond environment (OH)
3 Cl/Br, and atomic units O–Cu–O, Cu–O and Cl/Br–Cu–Cl/Br, etc. These results can be propitious to the low temperature spectral property of α-Cu
2(OH)
3Cl and α-Cu
2(OH)
3Br which must help to understand the underlying physics of their exotic geometric frustration phenomena at low temperatures. |
| doi_str_mv | 10.1016/j.vibspec.2011.02.002 |
| format | article |
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cm
−1) absorption and Raman (4000–95
cm
−1) spectra of the series of geometrically frustrated materials, botallackite-structure basic copper halides, α-Cu
2(OH)
3Cl and α-Cu
2(OH)
3Br polycrystalline samples were first, to the best of our knowledge, measured, respectively, to study the corresponding relationship between their vibrational spectral properties and crystal microstructures. Through the comparative analysis to the four spectra, the authors have definitely assigned or tentatively suggested the vibrational modes of hydroxyl groups in the trimeric hydrogen bond environment (OH)
3 Cl/Br, and atomic units O–Cu–O, Cu–O and Cl/Br–Cu–Cl/Br, etc. These results can be propitious to the low temperature spectral property of α-Cu
2(OH)
3Cl and α-Cu
2(OH)
3Br which must help to understand the underlying physics of their exotic geometric frustration phenomena at low temperatures.</description><identifier>ISSN: 0924-2031</identifier><identifier>EISSN: 1873-3697</identifier><identifier>DOI: 10.1016/j.vibspec.2011.02.002</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Botallackite ; Copper ; Crystals ; Frustration ; Geometrical frustration ; Halides ; Hydrogen bonds ; Microstructure ; Mid-infrared spectrum ; Raman spectrum ; Spectra ; Spectroscopy ; Vibrational spectrum</subject><ispartof>Vibrational spectroscopy, 2011-07, Vol.56 (2), p.177-183</ispartof><rights>2011 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c341t-8451593ca3607b7c09b3babd1619d6c8ba4ca1f55a1150625f4c3d3a5e7e7b4d3</citedby><cites>FETCH-LOGICAL-c341t-8451593ca3607b7c09b3babd1619d6c8ba4ca1f55a1150625f4c3d3a5e7e7b4d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Liu, Xiao-Dong</creatorcontrib><creatorcontrib>Hagihala, Masato</creatorcontrib><creatorcontrib>Zheng, Xu-Guang</creatorcontrib><creatorcontrib>Guo, Qi-Xin</creatorcontrib><title>Vibrational spectroscopic properties of botallackite-structure basic copper halides</title><title>Vibrational spectroscopy</title><description>Mid-infrared (4000–400
cm
−1) absorption and Raman (4000–95
cm
−1) spectra of the series of geometrically frustrated materials, botallackite-structure basic copper halides, α-Cu
2(OH)
3Cl and α-Cu
2(OH)
3Br polycrystalline samples were first, to the best of our knowledge, measured, respectively, to study the corresponding relationship between their vibrational spectral properties and crystal microstructures. Through the comparative analysis to the four spectra, the authors have definitely assigned or tentatively suggested the vibrational modes of hydroxyl groups in the trimeric hydrogen bond environment (OH)
3 Cl/Br, and atomic units O–Cu–O, Cu–O and Cl/Br–Cu–Cl/Br, etc. These results can be propitious to the low temperature spectral property of α-Cu
2(OH)
3Cl and α-Cu
2(OH)
3Br which must help to understand the underlying physics of their exotic geometric frustration phenomena at low temperatures.</description><subject>Botallackite</subject><subject>Copper</subject><subject>Crystals</subject><subject>Frustration</subject><subject>Geometrical frustration</subject><subject>Halides</subject><subject>Hydrogen bonds</subject><subject>Microstructure</subject><subject>Mid-infrared spectrum</subject><subject>Raman spectrum</subject><subject>Spectra</subject><subject>Spectroscopy</subject><subject>Vibrational spectrum</subject><issn>0924-2031</issn><issn>1873-3697</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkEtLAzEUhYMoWKs_QZidqxlz85jHSqT4goILH9uQZO5g6rQZk7Tgvzel3bu6m-8czv0IuQZaAYX6dlXtnIkT2opRgIqyilJ2QmbQNrzkddeckhntmCgZ5XBOLmJcUUprCXxG3j6dCTo5v9Fjse9IwUfrJ2eLKfgJQ3IYCz8Uxic9jtp-u4RlTGFr0zZgYXTMaA5ktPjSo-sxXpKzQY8Rr453Tj4eH94Xz-Xy9ellcb8sLReQylZIkB23mte0MY2lneFGmx5q6PratkYLq2GQUgNIWjM5CMt7riU22BjR8zm5OfTmpT9bjEmtXbSYV27Qb6Nq204I3nCWSXkgbf4uBhzUFNxah18FVO0dqpU6OlR7h4oylR3m3N0hh_mNncOgonW4sdi7kFWp3rt_Gv4AVtx_OA</recordid><startdate>20110718</startdate><enddate>20110718</enddate><creator>Liu, Xiao-Dong</creator><creator>Hagihala, Masato</creator><creator>Zheng, Xu-Guang</creator><creator>Guo, Qi-Xin</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20110718</creationdate><title>Vibrational spectroscopic properties of botallackite-structure basic copper halides</title><author>Liu, Xiao-Dong ; Hagihala, Masato ; Zheng, Xu-Guang ; Guo, Qi-Xin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c341t-8451593ca3607b7c09b3babd1619d6c8ba4ca1f55a1150625f4c3d3a5e7e7b4d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Botallackite</topic><topic>Copper</topic><topic>Crystals</topic><topic>Frustration</topic><topic>Geometrical frustration</topic><topic>Halides</topic><topic>Hydrogen bonds</topic><topic>Microstructure</topic><topic>Mid-infrared spectrum</topic><topic>Raman spectrum</topic><topic>Spectra</topic><topic>Spectroscopy</topic><topic>Vibrational spectrum</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Xiao-Dong</creatorcontrib><creatorcontrib>Hagihala, Masato</creatorcontrib><creatorcontrib>Zheng, Xu-Guang</creatorcontrib><creatorcontrib>Guo, Qi-Xin</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Vibrational spectroscopy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Xiao-Dong</au><au>Hagihala, Masato</au><au>Zheng, Xu-Guang</au><au>Guo, Qi-Xin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Vibrational spectroscopic properties of botallackite-structure basic copper halides</atitle><jtitle>Vibrational spectroscopy</jtitle><date>2011-07-18</date><risdate>2011</risdate><volume>56</volume><issue>2</issue><spage>177</spage><epage>183</epage><pages>177-183</pages><issn>0924-2031</issn><eissn>1873-3697</eissn><abstract>Mid-infrared (4000–400
cm
−1) absorption and Raman (4000–95
cm
−1) spectra of the series of geometrically frustrated materials, botallackite-structure basic copper halides, α-Cu
2(OH)
3Cl and α-Cu
2(OH)
3Br polycrystalline samples were first, to the best of our knowledge, measured, respectively, to study the corresponding relationship between their vibrational spectral properties and crystal microstructures. Through the comparative analysis to the four spectra, the authors have definitely assigned or tentatively suggested the vibrational modes of hydroxyl groups in the trimeric hydrogen bond environment (OH)
3 Cl/Br, and atomic units O–Cu–O, Cu–O and Cl/Br–Cu–Cl/Br, etc. These results can be propitious to the low temperature spectral property of α-Cu
2(OH)
3Cl and α-Cu
2(OH)
3Br which must help to understand the underlying physics of their exotic geometric frustration phenomena at low temperatures.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.vibspec.2011.02.002</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0924-2031 |
| ispartof | Vibrational spectroscopy, 2011-07, Vol.56 (2), p.177-183 |
| issn | 0924-2031 1873-3697 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_889443732 |
| source | Elsevier |
| subjects | Botallackite Copper Crystals Frustration Geometrical frustration Halides Hydrogen bonds Microstructure Mid-infrared spectrum Raman spectrum Spectra Spectroscopy Vibrational spectrum |
| title | Vibrational spectroscopic properties of botallackite-structure basic copper halides |
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