Stereodifferentiation in the Compartmentalized Photooxidation of a Protein-Bound Anthracene

Encapsulation within transport proteins strongly reduces the photooxidation rate of (S)- and (R)-2-(9-anthracenyl)propanoic acid (1) and results in a significant stereodifferentiation. The most remarkable effects are observed within human serum albumin (HSA).

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Bibliographic Details
Published in:Organic letters 2011-08, Vol.13 (15), p.3860-3863
Main Authors: Alonso, Rafael, Jiménez, M. Consuelo, Miranda, Miguel A
Format: Article
Language:English
Subjects:
Animals
Anthracenes - chemistry
Humans
Kinetics
Molecular Structure
Oxidation-Reduction
Photochemical Processes
Serum Albumin - chemistry
Stereoisomerism
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Description
Summary:Encapsulation within transport proteins strongly reduces the photooxidation rate of (S)- and (R)-2-(9-anthracenyl)propanoic acid (1) and results in a significant stereodifferentiation. The most remarkable effects are observed within human serum albumin (HSA).
ISSN:1523-7060
1523-7052
DOI:10.1021/ol201209h