Cyclopropanation with Gold(I) Carbenes by Retro-Buchner Reaction from Cycloheptatrienes

Cationic gold(I) promotes the retro-Buchner reaction of 7-substituted 1,3,5-cycloheptatrienes, leading to gold(I) carbenes that cyclopropanate alkenes.

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Bibliographic Details
Published in:Journal of the American Chemical Society 2011-08, Vol.133 (31), p.11952-11955
Main Authors: Solorio-Alvarado, César R, Wang, Yahui, Echavarren, Antonio M
Format: Article
Language:English
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Summary:Cationic gold(I) promotes the retro-Buchner reaction of 7-substituted 1,3,5-cycloheptatrienes, leading to gold(I) carbenes that cyclopropanate alkenes.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja205046h